| 磺基苯基卟啉金属配合物氧化还原催化性能的比较 |
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| 引用本文： | 杨长通 吴宝璋. 磺基苯基卟啉金属配合物氧化还原催化性能的比较[J]. 厦门大学学报(自然科学版), 1998, 37(6): 865-869 |
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| 作者姓名： | 杨长通 吴宝璋 |
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| 作者单位： | 厦门大学化学系 |
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| 基金项目： | 国家自然科学基金,国家教委博士学科点专项科研基金 |
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| 摘 要： | 用循环伏安法和旋转环盘电极技术研究中位－四－磺基苯基卟啉的铁、锰配合物（ＦｅＴＰＰＳ和ＭｎＴＰＰＳ）的氧化还原性能．比较均相溶液中它们对氧电还原的催化作用，发现ＦｅＴＰＰＳ的电催化活性优于ＭｎＴＰＰＳ，但尚依赖于溶液介质的性质．用电聚合方法将ＦｅＴＰＰＳ和ＭｎＴＰＰＳ分别嵌入聚吡咯中制成聚合物修饰电极，可改善电催化性能，不仅使氧还原电位正移，而且增大还原电流．讨论了聚合物修饰电极对氧还原的可能影响．
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| 关 键 词： | 金属卟啉，聚合物修饰电极，氧还原，电催化 |
Redox Catalytic Properties of Metal Complexes of Meso tetrakis (p sulfonatophenyl) Porphyrin: A Comparative |
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| Yang Changtong Wu Baozhang Wu Huihuang. Redox Catalytic Properties of Metal Complexes of Meso tetrakis (p sulfonatophenyl) Porphyrin: A Comparative[J]. Journal of Xiamen University(Natural Science), 1998, 37(6): 865-869 |
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| Authors: | Yang Changtong Wu Baozhang Wu Huihuang |
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| Abstract: | The redox properties of metal complexes of meso tetrakis(p sulfonatophenyl) porphyrin, FeTPPS and MnTPPS, were investigated by using cyclic voltammetry and RRDE technique. By comeprating the catalytic reduction of dioxygen in the presence of MTPPS in solution,it was found that the electrocatalytic activity of FeTPPS is superrior to MnTPPS, but depends on the nature of soluion media. MTPPS was incorporated into polypyrrole by electropolymerization of pyrrole, the as forming membrane electrodes facilitate the electroreduction of dioxygen. The role of polymer electrodes in oxygen reduction was discussed. |
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| Keywords: | Metalloporphyrins Polymer membrane modified electrodes Oxygen reduction Electrocatalysis |
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