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Sn/Sn3O4?x heterostructure rich in oxygen vacancies with enhanced visible light photocatalytic oxidation performance
Authors:Rui-qi Yang  Na Liang  Xuan-yu Chen  Long-wei Wang  Guo-xin Song  Yan-chen Ji  Na Ren  Ya-wei Lü  Jian Zhang  Xin Yu
Abstract:Sn3O4,a common two-dimensional semiconductor photocatalyst,can absorb visible light.However,owing to its rapid recombina-tion of photogenerated electron?hole pairs,its absorption is not sufficient for practical application.In this work,a Sn nanoparticle/Sn3O4?x nanosheetheterostructurewaspreparedbyin situreductionofSn3O4underaH2atmosphere.TheSchottkyjunctionsformedbetweenSnand Sn3O4?x can enhance the photogenerated carrier separation ability.During the hydrogenation process,a portion of the oxygen in the semicon-ductor can be extracted by hydrogen to form water,resulting in an increase in oxygen vacancies in the semiconductor.The heterostructure showed the ability to remove Rhodamine B.Cell cytocompatibility experiments proved that Sn/Sn3O4?x can significantly enhance cell compat-ibility and reduce harm to organisms.This work provides a new method for the fabrication of a Schottky junction composite photocatalyst rich in oxygen vacancies with enhanced photocatalytic performance.
Keywords:photocatalysis  tin oxide  oxygen vacancy  Schottky junction  photodegradation
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