| Synthesis and magnetic properties of one-dimensional Mn（Ⅱ） complexes linked by dithiooxalato |
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| 作者姓名： | CUIJianzhong SHIWei CHENGPeng CHENXufang LIAODaizheng YANShiping JIANGZonghui WANGGenglin |
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| 作者单位： | DepartmentofChemistry,NankaiUniversity,Tianjin300071,China |
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| 基金项目： | 国家自然科学基金，天津市自然科学基金，the TRAPOYT in Higher Education Institutions of MOE |
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| 摘 要： | Three dithiooxalato (Dto) bridging one-dimensional Mn(Ⅱ) complexes Mn(L)Dto](L=Phen (1), Bpy (2) and en (3)) were synthesized. All of the complexes have the similar one-dimensional structure through Dto bridge. The measurement of the variable temperature magnetic susceptibility of complex 1 showed that there are weak antiferromagnetic interactions between the Mn(Ⅱ) ions.
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| 关 键 词： | 一维结构 锰配合物 合成 反铁磁性 Dto 二硫代草酰胺 |
| 收稿时间： | 2002-07-30 |
| 修稿时间： | 2003-01-07 |
Synthesis and magnetic properties of one-dimensional Mn(II) complexes linked by dithiooxalato |
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| CUIJianzhong SHIWei CHENGPeng CHENXufang LIAODaizheng YANShiping JIANGZonghui WANGGenglin.Synthesis and magnetic properties of one-dimensional Mn(II) complexes linked by dithiooxalato[J].Chinese Science Bulletin,2003,48(9):859-861. |
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| Authors: | Jianzhong Cui Wei Shi Peng Cheng Xufang Chen Daizheng Liao Shiping Yan Zonghui Jiang Genglin Wang |
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| Institution: | CUI Jianzhong, SHI Wei, CHENG Peng, CHEN Xufang, LIAO Daizheng, YAN Shiping, JIANG Zonghui & WANG Genglin Department of Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | Three dithiooxalato (Dto) bridging one-dimensional Mn(Ⅱ) complexes Mn(L)Dto](L = Phen (1), Bpy (2) and en (3)) were synthesized. All of the complexes have the similar one-dimensional structure through Dto bridge. The measurement of the variable temperature magnetic susceptibility of complex 1 showed that there are weak antiferromag- netic interactions between the Mn(Ⅱ) ions. |
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| Keywords: | one-dimensional manganese(II) complex 2-dithioox-alato ESR magnetism |
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