| 四苯基卟啉的微波诱导合成研究 |
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| 引用本文： | 胡希明,梅治乾,刘海洋,黄仲涛,王乐夫.四苯基卟啉的微波诱导合成研究[J].华南理工大学学报(自然科学版),1999,27(10):11-15. |
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| 作者姓名： | 胡希明 梅治乾 刘海洋 黄仲涛 王乐夫 |
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| 作者单位： | 华南理工大学化工学院,广州,510640 |
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| 摘 要： | 研究了四苯基卟啉微波诱导合成的机理及影响因素。实验结果表明，微波作用的时间与强度、反应体系溶剂及催化剂的选择、反应试剂的组成及用量等均对四苯基卟啉的合成有较在的影响；微波对四苯基卟啉的合成存在非热效应，可提高反应试剂缩合关环形成四苯基卟啉的速率。
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| 关 键 词： | 四苯基卟啉 微波诱导 合成 |
| 修稿时间： | 1998-12-25 |
STUDY ON THE MICROWAVE-INDUCED SYNTHESIS OF TETRAPHENYLPORPHYRIN |
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| Hu Ximing,Mei Zhiqian,Liu Haiyang,Huang Zhongtao,Wang Lefu.STUDY ON THE MICROWAVE-INDUCED SYNTHESIS OF TETRAPHENYLPORPHYRIN[J].Journal of South China University of Technology(Natural Science Edition),1999,27(10):11-15. |
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| Authors: | Hu Ximing Mei Zhiqian Liu Haiyang Huang Zhongtao Wang Lefu |
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| Abstract: | The mechanism and factors of fmicrowave_induced synthesis of tetraphenylporphyrin (TPP) had been investigated. Our tests indicated that the synthesis was much influenced by the time and intensity of microwave irradiation, the choice of solvents and catalysts, the proportion and quantity of reactants and so on. Microwave inducement resulted in the athermal effect, which can increase the velocity of close_loop condensation reaction in the formation of TPP. |
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| Keywords: | tetraphenylporphyrin microwave inducement synthesis |
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