| (FeCp_2)_(0.13)〔Ni(C_3S_5)(C_3S_7)〕的合成及电化学性质的研究 |
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| 引用本文： | 陈晓红,李晓春,张文韬,杨宪立,王晓晖.(FeCp_2)_(0.13)〔Ni(C_3S_5)(C_3S_7)〕的合成及电化学性质的研究[J].内蒙古民族大学学报(自然科学版),2005(5). |
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| 作者姓名： | 陈晓红 李晓春 张文韬 杨宪立 王晓晖 |
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| 作者单位： | 内蒙古民族大学化学学院 内蒙古通辽028043
(陈晓红，张文韬，杨宪立)，赤峰学院 内蒙古赤峰024000
(李晓春)，内蒙古民族大学化学学院 内蒙古通辽028043(王晓晖) |
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| 基金项目： | 内蒙古自治区教育厅资助课题(NJ02071) |
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| 摘 要： | 首次合成了新型配位化合物(FeCp2)0.13〔Ni(C3S5)(C3S7)〕,配体为具有12个S原子的杂戊烯,通过EAI、CP、IR、1HNMR、UV对这种化合物进行了表征,并通过循环伏安法和变温四探针法对其电化学性质进行了研究.结果表明,硫链增长及二茂铁阳离子的引入使配合物的室温导电性能有了一定的改善.
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| 关 键 词： | 双二硫杂戊烯 (FeCp2)0.13〔Ni(C3S5)(C3S7)〕 合成 电化学性质 |
Synthesis and Electrochemical Behavaiorof(FeCp_2)_(0.13)(Ni(C_3S_5)(C_3S_7)) |
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| CHEN Xiao-hong,LI Xiao-chun,ZHANG Wen-tao,YANG Xian-li,WANG Xiao-hui.Synthesis and Electrochemical Behavaiorof(FeCp_2)_(0.13)(Ni(C_3S_5)(C_3S_7))[J].Journal of Inner Mongolia University for the Nationalities(Natural Sciences),2005(5). |
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| Authors: | CHEN Xiao-hong LI Xiao-chun ZHANG Wen-tao YANG Xian-li WANG Xiao-hui |
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| Institution: | CHEN Xiao-hong~1,LI Xiao-chun~2,ZHANG Wen-tao~1,YANG Xian-li~1,WANG Xiao-hui~1 |
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| Abstract: | One new coordination compound has been synthetized by introducing FeCp~(2+) catons into the system of(M(C_3S_5)(C_3S_7))~(n+) for the first time(M=Ni).Ligand is dithiole with twelve S atoms.It has been characterized by EA,ICP,IR,~1HNMR,UV and the electrochemical property also has been studied by cyclic voltammetary and four probe methods.It is concluded that the electrical property of the compound has been improved somewhat because of sulfur-chain growth and the introducing of FeCp~(2+) into the system of(Ni(C_3S_5)(C_3S_7))~(n-). |
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| Keywords: | Bis-dithiole (FeCp_2)_(0 13)(Ni(C_3S_5)(C_3S_7)) Synthesis Electrochemical behaviour |
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