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用高锰酸钠氧化法去除水中的苯胺
引用本文:任广军,翟玉春,田彦文,张伯松. 用高锰酸钠氧化法去除水中的苯胺[J]. 东北大学学报(自然科学版), 2003, 24(5): 475-477. DOI: -
作者姓名:任广军  翟玉春  田彦文  张伯松
作者单位:1. 东北大学材料与冶金学院,辽宁沈阳,110004
2. 沈阳市环境监测中心站,辽宁沈阳,110015
基金项目:辽宁省自然科学基金资助项目(0022054)
摘    要:研究了高锰酸钠对水中苯胺的去除作用·实验结果表明,随着高锰酸钠投加量的增加,水中苯胺的去除率增加,在苯胺初始质量浓度为10mg/L,温度为18℃,pH值为6 8,反应时间为30min的条件下,高锰酸钠质量浓度为30mg/L时,苯胺的去除率达92 12%·水样的pH值对苯胺去除效果有较大影响,在强酸性及强碱性条件下苯胺去除效果高于中性条件,pH值为3时,苯胺去除率为97 55%;pH值为11时,苯胺去除率为96 33%·升高温度或延长反应时间对苯胺的去除均有正的影响·苯胺是通过高锰酸根和新生态的氧将其氧化成苯醌而去除的·

关 键 词:水处理  高锰酸钠  氧化  苯胺去除率
文章编号:1005-3026(2003)05-0475-03
修稿时间:2002-11-19

Eliminating Aniline in Water by Sodium Permanganate Oxidation
Ren,Guang-Jun ,Zhai,Yu-Chun ,Tian,Yan-Wen ,Zhang,Bo-Song. Eliminating Aniline in Water by Sodium Permanganate Oxidation[J]. Journal of Northeastern University(Natural Science), 2003, 24(5): 475-477. DOI: -
Authors:Ren  Guang-Jun   Zhai  Yu-Chun   Tian  Yan-Wen   Zhang  Bo-Song
Affiliation:(1) Sch. of Mat. and Metall., Northeastern Univ., Shenyang 110004, China; (2) Environ. Monitoring Central Station, Shenyang 110015, China
Abstract:Eliminating aniline in water was investigated by sodium permanganate. It is showed that with the increase of sodium permanganate, aniline eliminating rate increases. Aniline eliminating rate reaches 92.12% by the condition of aniline concentration lO mg/L, temperature 18°C ,pH 6.8, reaction time 30 min and sodium permanganate 30 mg/L. The pH value of water sample plays a role on aniline elimination. The effect of removing aniline in alid or alkaline solutions is more significant than in neutral water. The aniline eliminating rate is 97.55% at pH value 3 and 96.33% at pH value 11. Increasing the temperature or the reaction time has good effects on removing aniline. By the cooperation of permanganate and the formed oxygen, aniline is oxidated into guinone and removed.
Keywords:?water treatment  sodium permanganate  oxidation  aniline  eliminating rate
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