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纳米复合水凝胶的制备与表征
引用本文:容建华,陈敏,胡永红,刘应亮.纳米复合水凝胶的制备与表征[J].暨南大学学报,2005,26(5):657-661.
作者姓名:容建华  陈敏  胡永红  刘应亮
作者单位:暨南大学化学系,广东,广州,510632
基金项目:广东省自然科学基金(04300643).暨南大学引进优秀人才科研启动基金(692015)资助项目
摘    要:以两种不同的黏土-锂基黏土XLG和钠基黏土(Na—clay)为改性剂,通过原位复合法制备黏土/聚丙烯酰胺复合水凝胶.通过调整反应物之间的配比、反应条件考察了纳米复合水凝胶的机械强度、吸胀性能、透明性等性能.结果表明两种黏土都能够增强水凝胶的拉伸强度,其中前者效果更加明显.并且XLG/聚台物凝胶具有极好的透明度,XRD结果表明黏土在聚合物基体中呈纳米尺度均匀分散,并起到交联剂作用.

关 键 词:水凝胶  黏土  纳米  聚丙烯酰胺
文章编号:1000-9965(2005)05-0657-05
收稿时间:09 8 2004 12:00AM
修稿时间:2004年9月8日

Preparation and characterization of nanocomposite hydrogels
RONG Jian-hua,CHEN Min,HU Yong-hong,LIU Ying-liang.Preparation and characterization of nanocomposite hydrogels[J].Journal of Jinan University(Natural Science & Medicine Edition),2005,26(5):657-661.
Authors:RONG Jian-hua  CHEN Min  HU Yong-hong  LIU Ying-liang
Institution:Department of Chemistry, Jinan University, Guangzhou 510632, China
Abstract:Clay/Polyacryamide composite hydmgels were prepared via in - situ polymerization by using two kind of clay as modifier. The mechanical property, water absorption, nanostincture and transparency were characterized. It shows that both clay XLG and Na- clay, especially the former can reinforce the hydmgel. And the great transparency and the XRD results of polyacrylamide/XLG hydrogel show that the nanoparticles of XLG were dispersed homogenously in polymer matrix while acting as physical cmsslinker.
Keywords:hydrogel  clay  nanometer  polyacrylamide
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