| 1,3-二羟甲基-5-氟尿嘧啶的合成及其配位性质研究 |
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| 引用本文： | 吴燕.1,3-二羟甲基-5-氟尿嘧啶的合成及其配位性质研究[J].淮阴师范学院学报(自然科学版),2009,8(1). |
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| 作者姓名： | 吴燕 |
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| 作者单位： | 云南省永善县第一中学,云南,永善,657300 |
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| 摘 要： | 5-氟尿嘧啶(5-FU)与甲醛在水中,以碳酸钾为催化剂回流8 h,合成了1,3-二羟甲基-5-氟尿嘧啶.并通过合成1,3-二羟甲基-5-氟尿嘧啶-1,10-邻菲咯啉-过渡金属三元配合物及1,3-二羟甲基-5-氟尿嘧啶-1,10-邻菲咯啉-2-氨基吡啶-过渡金属四元配合物两个系列配合物,研究了其配位性质,通过红外光谱、紫外-可见光谱、荧光光谱等手段对化合物进行了表征.
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| 关 键 词： | 5-氟尿嘧啶 1-羟甲基-5-氟尿嘧啶 配合物 |
Synthesis and Characterization of 1,3-dimethylol-5-fluorouracil and Its Transition Metal Complexes |
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| WU Yan.Synthesis and Characterization of 1,3-dimethylol-5-fluorouracil and Its Transition Metal Complexes[J].Journal of Huaiyin Teachers College(Natrual Science Edition),2009,8(1). |
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| Authors: | WU Yan |
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| Institution: | No.One Middle School of Yongshan County;Yongshan Yunnan 657300;China |
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| Abstract: | 1,3-dimethylol-5-fluorouracil was synthesized and characterized by the reaction of 5-fluorouracil(5-FU) and formaldehyde in water catalyzed by potassium carbonate in this paper.Two serials of ternary complexes of 1,3-dimethylol5-fluorouracil were synthesized to research its coordinative property and the complexes were characterized by UV(visible-ultraviolet spectra),fluorescence spectra and IR(infrared spectra) in the second part. |
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| Keywords: | 5-fluorouracil 1 3-dimethylol-5-fluorouracil complex |
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