| 重氮乙酸乙酯与烯胺的新反应研究 |
| |
| 引用本文： | 赵伟杰,闫凤美.重氮乙酸乙酯与烯胺的新反应研究[J].河南科学,2006,24(4):499-501. |
| |
| 作者姓名： | 赵伟杰 闫凤美 |
| |
| 作者单位： | 黄淮学院化学化工系,河南,驻马店,463000 |
| |
| 摘 要： | 主要论述重氮乙酸乙酯(EDA)与N-(苯乙烯基-)吗啉在铜盐催化下的反应,能够以较高的化学产率制备4-氧代-4-苯基-丁酸乙酯.我们详细考察了催化剂、反应溶剂以及反应温度对这一反应的影响.
|
| 关 键 词： | 重氮乙酸乙酯 烯胺 铜盐催化剂 4-氧代-4-苯基-丁酸乙酯 |
| 文章编号： | 1004-3918(2006)04-0499-03 |
| 收稿时间： | 2006-03-02 |
| 修稿时间： | 2006年3月2日 |
Study on the New Reaction of Enamines with Ethyl Diazoacetate |
| |
| ZHAO Wei-jie,YAN Feng-mei.Study on the New Reaction of Enamines with Ethyl Diazoacetate[J].Henan Science,2006,24(4):499-501. |
| |
| Authors: | ZHAO Wei-jie YAN Feng-mei |
| |
| Institution: | Department of Chemistry and Chemical Engineering, Huanghuai College, Zhumadian 463000, China |
| |
| Abstract: | The reaction of ethyl diazoacetate(EDA) with N-(styryl)morpholine catalyzed by copper salts provided ethyl 4-oxo-4-phenylbutanoate: in good yield.A full investigation of the effects of solvents,catalysts,temperature on the reaction was carried out. |
| |
| Keywords: | ethyl diazoacetate Copper salt catalyst Enamine ethyl 4-oxo-4-phenylbutanoate |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
