| 双羰基化合物的Wittig反应 |
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| 引用本文： | 陈家威 蒋济隆. 双羰基化合物的Wittig反应[J]. 湖北大学学报(自然科学版), 1989, 11(1): 65-68 |
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| 作者姓名： | 陈家威 蒋济隆 |
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| 作者单位： | 湖北大学化学系(陈家威，蒋济隆)，湖北大学化学系(钟建华) |
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| 摘 要： | 以二甲基亚砜钠和苯基锂为碱,对双羰基化合物的Wittig反应进行了初步的研究.对苯二甲醛的单Wittig产率为30～41%,而双Wittig产率则为12～15%;脂肪二醛的单Wittig产率为0,而双Wittig产率为12～15%;二酮的两种产率都为0.
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| 关 键 词： | 二羰基化合物 Wittig反应 叶立德 |
THE WITTIG REACTIONS OF DICARBONYL COMPOUNDS |
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| Chen Jiawei Jiang Jilong Zhong Jianhua. THE WITTIG REACTIONS OF DICARBONYL COMPOUNDS[J]. Journal of Hubei University(Natural Science Edition), 1989, 11(1): 65-68 |
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| Authors: | Chen Jiawei Jiang Jilong Zhong Jianhua |
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| Affiliation: | Department of Chemistry |
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| Abstract: | The Wittig reactions of dicarbonyl compounds were researched using sodium dimethyl sulfoxide or phenyllithium as base. The single Wittig yields of terephthalaldehyde were 30-41%, but the double Wittig yields were 12-15%. The single Wittig yields of the aliphatic dialdehydes were O, while the double Wittig yields were 12-15%. The single and double Wittig yields of diketones were O. |
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| Keywords: | Wittig reaction ylide dicarbonyl compounds. |
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