| 离子选择电极在混合溶剂中的应用Ⅱ．Cu（Ⅱ）与甘氨酸配合物在醇＋水溶剂中的稳定常数 |
| |
| 引用本文： | 樊静,夏志清,黄豪.离子选择电极在混合溶剂中的应用Ⅱ．Cu（Ⅱ）与甘氨酸配合物在醇＋水溶剂中的稳定常数[J].河南师范大学学报(自然科学版),1994(1). |
| |
| 作者姓名： | 樊静 夏志清 黄豪 |
| |
| 作者单位： | 河南师范大学化学系，南阳师专 |
| |
| 基金项目： | 河南省教委青年自然科学基金资助 |
| |
| 摘 要： | 本文利用离子选择电极法测定了２５℃，Ⅰ＝０．１时，钢（Ⅱ）－甘氨酸配合物在纯水及８．０％，１６．３％，２５．０％，３４．２％，４３．８％叔丁醇或异丙醇＋水混合溶剂中的一级稳定常数，计算了配位反应的自由能变化及该配位反应从纯水到上述各混合溶剂的转移自由能。实验结果表明：随着混合溶剂中有机组分的加入，配合物更趋于稳定．
|
| 关 键 词： | 离子选择电极 混合溶剂 铜络合物 稳定常数 |
Use of Ion Selective Electrode in Mixed Solvents Ⅱ. Stability Constants of Cu(Ⅱ)-Glycine Complex in Aleohol+Water Solvents |
| |
| Fan Jing Xia Zhiqing et al.Use of Ion Selective Electrode in Mixed Solvents Ⅱ. Stability Constants of Cu(Ⅱ)-Glycine Complex in Aleohol+Water Solvents[J].Journal of Henan Normal University(Natural Science),1994(1). |
| |
| Authors: | Fan Jing Xia Zhiqing |
| |
| Abstract: | The first stability constants of Cu(Ⅱ)-glycine complex in water and in 8.0%,16.3%,25.0%,34.2%,43.8%(w/w)t-butyl alcohol(TBA)or isopropyl alcohol (IPA)+ watermixed solvents have been determined by ISE method at 25℃and I=0.1.The free cnergies for complex re-action in the respcctive solvents and the tranfer free energies for complex reaction from water to a series ofmixed solvents have been calculated.It has been shown that stability of the complex incrcases with in-creasing TBA or IPA content in mixed solvents. |
| |
| Keywords: | ion selective electrode mixed solvent copper complex stability constant |
| 本文献已被 CNKI 等数据库收录！ |
