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| 八氨基苯基笼型倍伴硅氧烷合成方法的优化 | |
| 引用本文： | 侯俊萍,张丽影,赵小菁,范圣第,陈平. 八氨基苯基笼型倍伴硅氧烷合成方法的优化[J]. 大连民族学院学报, 2013, 15(5): 489-492 |
| 作者姓名： | 侯俊萍 张丽影 赵小菁 范圣第 陈平 |
| 作者单位： | 1. 大连民族学院生物化学工程国家民委-教育部重点实验室,辽宁大连,116605 2. 大连民族学院生物化学工程国家民委-教育部重点实验室,辽宁大连116605;大连理工大学先进聚合物基复合材料制备技术辽宁省重点实验室,辽宁大连116012 3. 大连理工大学先进聚合物基复合材料制备技术辽宁省重点实验室,辽宁大连,116012 |
| 基金项目： | 中央高校基本科研业务费专项资金资助项目 |
| 摘 要： | 以八硝基苯基笼型倍伴硅氧烷（ONPS）为原料，三氯化铁／活性炭为催化剂，乙二醇甲醚为溶剂，采用水合肼还原法合成了OAPS，优化了OAPS的合成方法，收率达到83．67％；利用FTIR、uV、XRD、EA等分析手段，对OAPS的结构进行了表征；通过热失重分析，验证了OAPS的热稳定性。该方法简化了后处理步骤，降低了合成成本。 |
| 关 键 词： | 笼型倍伴硅氧烷 八氨基苯基倍伴硅氧烷（OAPS） 合成与表征 |
Optimal Synthesis of Octa Aminophenyl Polyhedral Silsesquioxane |
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| HOU Jun-ping , ZHANG Li-ying , ZHAO Xiao-jing , FAN Sheng-di , CHEN Ping. Optimal Synthesis of Octa Aminophenyl Polyhedral Silsesquioxane[J]. Journal of Dalian Nationalities University, 2013, 15(5): 489-492 | |
| Authors: | HOU Jun-ping ZHANG Li-ying ZHAO Xiao-jing FAN Sheng-di CHEN Ping |
| Affiliation: | Key Laboratory of the State Ethnic Affairs Commission - Ministry of Education, Dalian Nationalities University, Dalian Nationalities University, Dalian Liaoning 116605, China; . Liaoning Key Laboratory of Advanced Polymer Matrix Composites Manufacturing Technology, Dalian University of Technology, Dalian Liaoning 116012, China) |
| Abstract: | Octa nitrophenyl polyhedral silsesquioxane （ONPS） was successfully reduced to octa aminophenyl polyhedral silsesquioxane （OAPS） using hydrazine hydrate as reducing agent, FeC13 6H20/C as catalyst and ethylene glycol monomethyl ether as solvent. The synthesis method of OAPS was optimized, and the yield reached 83.67%. The structures of OAPS were characterized by means of FTIR, XRD, UV, EA. The thermal stability of OAPS was verified by TG. This method simplified the synthesis processing of OAPS and reduced the cost of syn- thesis. |
| Keywords: | polyhedral oligomeric silsesquioxane octa aminophenyl polyhedral silsesquioxane synthesis and characterization |
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