| 不同电极基体对K2FeO4充放电循环性能的影响 |
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| 引用本文： | 杨卫华.不同电极基体对K2FeO4充放电循环性能的影响[J].华侨大学学报(自然科学版),2006,27(2):151-154. |
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| 作者姓名： | 杨卫华 |
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| 作者单位： | 华侨大学材料科学与工程学院,福建,泉州,362021 |
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| 基金项目： | 福建省自然科学基金;福建省青年科技人才创新基金;华侨大学校科研和教改项目 |
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| 摘 要： | 采用三电极体系法研究银网、铂网和泡沫镍等不同电极基体的阳极极化行为,探讨不同电极基体对 K_2FeO_4电极充放电性能的影响规律．结果表明,K_2FeO_4具有一定的可充性,但其充放电性能与电极基体的析氧电位有很大关系．电极基体的析氧电位低于K_2FeO_4的氧化还原电位时,K_2FeO_4电极基本充不上电;而当电极基体的析氧电位与K_2FeO_4的氧化还原电位相近,K_2FeO_4电极只能部分充电．
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| 关 键 词： | K_2FeO_4 阳极极化 充放电性能 电极基体 |
| 文章编号： | 1000-5013（2006）02-0151-04 |
| 收稿时间： | 2005-10-10 |
| 修稿时间： | 2005-10-10 |
The Effects of Electrode Metals on the Charge-Discharge Behavior of K2FeO4 Electrodes |
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| Yang Weihua.The Effects of Electrode Metals on the Charge-Discharge Behavior of K2FeO4 Electrodes[J].Journal of Huaqiao University(Natural Science),2006,27(2):151-154. |
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| Authors: | Yang Weihua |
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| Institution: | College of Material Science and Engineering, Huaqiao University, 362021, Quanzhou, China |
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| Abstract: | In order to understand the effects of electrode materials on the charge-discharge behaviors of K_2FeO_4 electrodes , constant current charge-discharge experiments were carried out to investigate the charge-discharge performance of K_2FeO_4 electrodes using silver lattice, nickel foam and platinum lattice as current collectors respectively. Polarization curves of these metal materials were used to interpret the difference in the charge-discharge performance of the corresponding K_2FeO_4 electrodes. Studies showed that the K_2FeO_4 electrodes have low electrochemical reversibility, which may be mainly resulted from their relatively lower oxygen evolution potentials or the effects of the oxidation/reduction process of current collectors. |
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| Keywords: | K_2FeO_4 polarization curve charge-discharge behavior electrode metals |
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