| 硅胶整体柱的制备 |
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| 引用本文： | 马小东,杨更亮,宋秀荣,孙素芳,刘海燕,李海鹰. 硅胶整体柱的制备[J]. 河北大学学报(自然科学版), 2002, 22(3): 261-263. DOI: 10.3969/j.issn.1000-1565.2002.03.014 |
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| 作者姓名： | 马小东 杨更亮 宋秀荣 孙素芳 刘海燕 李海鹰 |
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| 作者单位： | 1.河北大学,化学与环境科学学院,河北,保定,071002;承德卫生学校,河北,承德,067000； 2.河北大学,化学与环境科学学院,河北,保定,071002 |
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| 基金项目： | 国家自然科学基金资助项目 (2 0 0 75 0 0 5 )，河北省自然科学基金资助项目 (2 0 0 0 77) |
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| 摘 要： | 研究了硅胶整体柱的制备工艺及温度、pH值对凝胶化过程的影响,探讨了凝胶形成的机理.结果表明,以四甲氧基硅烷及聚乙二醇为原料,采用改进的溶胶-凝胶工艺制备的硅胶整体柱,具有微米级鞍形骨架、微米级大孔和纳米级中孔,适合于对大分子量的样品进行高效、快速的分离.
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| 关 键 词： | 四甲氧基硅烷 聚乙二醇 硅胶整体柱 溶胶-凝胶 |
| 文章编号： | 1000-1565(2002)03-0261-03 |
| 修稿时间： | 2001-12-10 |
Preparation of Monolithic Silica Gel Column |
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| MA Xiao dong ,,YANG Geng liang ,SONG Xiu rong ,SUN Su fang ,LIU Hai yan ,LI Hai ying. Preparation of Monolithic Silica Gel Column[J]. Journal of Hebei University (Natural Science Edition), 2002, 22(3): 261-263. DOI: 10.3969/j.issn.1000-1565.2002.03.014 |
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| Authors: | MA Xiao dong YANG Geng liang SONG Xiu rong SUN Su fang LIU Hai yan LI Hai ying |
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| Affiliation: | MA Xiao dong 1,2,YANG Geng liang 1,SONG Xiu rong 1,SUN Su fang 1,LIU Hai yan 1,LI Hai ying 1 |
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| Abstract: | A approach of preparation of monolithic silica column was reported, in which tetramethoxysilane and poly ethylene glycol were used as the material. An improved sol-gel process was adopted. The monolithic silica column has continuous gel skeletons and through-pores together with open mesopores. It has the advantage to separate samples with high-efficiency and high-speed. The effects of pH value and temperature of water-bath on the process of gelation were investigated and the mechanism of morphology was also discussed. |
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| Keywords: | tetramethoxysilane poly ethylene glycol monolithic silica column sol-gel |
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