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镧-溴邻苯三酚红-亚甲蓝配合物的紫外可见光谱研究
引用本文:杨月辉,霍国燕,何丽丽,孟祥军. 镧-溴邻苯三酚红-亚甲蓝配合物的紫外可见光谱研究[J]. 河北大学学报(自然科学版), 1992, 0(3)
作者姓名:杨月辉  霍国燕  何丽丽  孟祥军
作者单位:河北大学化学系(杨月辉,霍国燕,何丽丽),河北大学化学系(孟祥军)
摘    要:本文研究了镧的溴邻苯三酚红配离子与亚甲蓝形成沉淀的最佳条件,测定了沉淀的组成和溶度积,研究了该三元离子对体系的吸光性质,可作为沉淀、分离、高灵敏协同显色反应测定微量镧的新方法。

关 键 词:  溴邻苯三酚红  亚甲蓝

The UV-VIS Spectra Study on Coordination Compound of Lanthanum with Bromopyrogallol Red and Methylene Blue
Yang Yuehui Huo Guoyan He Lili Meng Xiangjun. The UV-VIS Spectra Study on Coordination Compound of Lanthanum with Bromopyrogallol Red and Methylene Blue[J]. Journal of Hebei University (Natural Science Edition), 1992, 0(3)
Authors:Yang Yuehui Huo Guoyan He Lili Meng Xiangjun
Affiliation:Department of Chemistry
Abstract:Lanthanum ion reacts with bromopyrogallol red at oplimurn pH5.5~ 6.0 to give a blue complex which reacts with methylene blue to give an isochromatic ion-pair complex. The association capability and the absorption properties of the ion-pair system were studied Owing to the isochromatic effect of the ion-pairs, the sensitivity for the dctermination of lanthanum is enhanced .It can be used as a new method in the determination of lanthanum (Ⅲ)
Keywords:Lanthanum   Bromopyrogallol red    Methyiene bule.
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