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苯乙烯正辛烷混合液密度黏度的测定及关联
引用本文:马沛生,金会义,李楠楠,杨长生.苯乙烯正辛烷混合液密度黏度的测定及关联[J].天津大学学报(自然科学与工程技术版),2005,38(4):356-360.
作者姓名:马沛生  金会义  李楠楠  杨长生
作者单位:天津大学化工学院,天津300072
摘    要:为提供工程设计和放大所需的物性数据和热力学数据,在常压下分别采用U形震动管密度计和乌氏黏度计测定了苯乙烯正辛烷混合液在293.15~363.15 K的密度黏度,计算了超额体积VE以及不同温度组成下的混合黏度的变化,对不同温度下超额体积和黏度变化与组成的关系分别用Redlich-Kister方程进行关联,混合黏度用Andrade公式进行关联.

关 键 词:密度  黏度  超额摩尔体积  苯乙烯  正辛烷
文章编号:0493-2137(2005)04-0356-05
修稿时间:2003年12月3日

Densities and Viscosities for Binary Mixture of the Styrene with n-Octane at Different Temperatures
MA Pei-sheng,JIN Hui-yi,LI Nan-nan,YANG Chang-sheng.Densities and Viscosities for Binary Mixture of the Styrene with n-Octane at Different Temperatures[J].Journal of Tianjin University(Science and Technology),2005,38(4):356-360.
Authors:MA Pei-sheng  JIN Hui-yi  LI Nan-nan  YANG Chang-sheng
Abstract:In order to get the data of substance character and thermodynamics used in engineering design and scale-up,densities and viscosities of the binary mixture of styrene with n-octane were determined between (293.15) K and 363.15 K under atmospheric pressure by using a vibrating U-shaped sample tube densimeter and Ubbelohde suspended-level viscometer.Density values were used in the determination of excess molar volume.Viscosities were used to calculate the deviations of viscosity.Excess volume and deviation of viscosity were fitted by the Redlich-Kister equation.Viscosities were done by the Andrade equation.
Keywords:density  viscosity  excess molar volume  styrene  n-octane  
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