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氨基酸衍生物的BZ类振荡反应(Ⅰ)振荡现象及其影响因素的研究
引用本文:沈振文,褚亮,陈梓元.氨基酸衍生物的BZ类振荡反应(Ⅰ)振荡现象及其影响因素的研究[J].上海师范大学学报(自然科学版),1995(2).
作者姓名:沈振文  褚亮  陈梓元
摘    要:本文报道氨基酸的衍生物与丙酮作混合底物的BZ类振荡反应[KBrO3-(CH3O)3CCH(NH2)COOH-CH3COCH3-MnSO4-H2SO4]体系的振荡反应.给出了典型振荡波形及振荡浓度范围,分析了对振荡反应影响的因素、温度效应.解释了两种有机底物在振荡反应中的作用,并初步探讨了反应的机理。

关 键 词:振荡反应  三羟甲基甲基甘氨酸  混合底物

BZ-Like Oscillating Reaction with Derivative of Amino Acid I Study on Oscillating Phenomena and Effects of Some Factors
shen Zhenwen,Zhu Laing,Chen Zhiyuan.BZ-Like Oscillating Reaction with Derivative of Amino Acid I Study on Oscillating Phenomena and Effects of Some Factors[J].Journal of Shanghai Normal University(Natural Sciences),1995(2).
Authors:shen Zhenwen  Zhu Laing  Chen Zhiyuan
Institution:Department of Chemistry
Abstract:The BZ-like chemical oscillating reaction in the system of KBrO3-(CH3O)3CCH (NH2) COOH-CH3COCH3-MnSO4-H2SO4 is investigated. The typical oscillating wave and the concentration ranges of oscillation are shown. Effects of some factors on the oscillation and temperature effect are analysed. The roles of two organic substrates in the oscillation are accounted and the mechanism of the reaction is explored.
Keywords:oscillating reaction  tricine  mixed substrates
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