| 用群论研究MX5Y型配合物的红外和拉曼光谱 |
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| 引用本文： | 马立扬,康衡.用群论研究MX5Y型配合物的红外和拉曼光谱[J].湖南师范大学自然科学学报,1989,12(1):48-53. |
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| 作者姓名： | 马立扬 康衡 |
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| 作者单位： | 湘潭大学化学系，湖南师大化学系 |
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| 摘 要： |
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| 关 键 词： | 配合物 MX5Y型 群论 光谱 钴 |
STUDY ON IR AND RAMAN SPECTRA OF MX_5Y COMPLEXES BY USING GROUP THEORY |
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| Ma Liyang.STUDY ON IR AND RAMAN SPECTRA OF MX_5Y COMPLEXES BY USING GROUP THEORY[J].Journal of Natural Science of Hunan Normal University,1989,12(1):48-53. |
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| Authors: | Ma Liyang |
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| Institution: | Ma Liyang Department of Chemistry,Xiangtan University Kang Heng Department of Chemistry,Hunan Normal University |
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| Abstract: | Co(NH_3)_5Cl]Cl_2 andCo(NH_3)_5H_2O]Cl_3 belong to the C_(4v) point group.Weexamine their vibrations with group theory,it turns out that their fifteen normalvibrations are reduced to eleven vibrational modes and four symmetry species.That is 4A_1,2B_1,B_2 and 4E.All vibrational modes are Raman active,A_1 andEare IR active,whereas B_1 and B_2 are forbidden in IR.The frequencies of IRand Raman spectra resulted from these vibrations are analyzed and answered theirassigning problems. |
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| Keywords: | spectral classification Raman spectrometry group representation/IR spectra |
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