| 高区域选择合成对位柑菁酸甲酯中催化作用机理的研究 |
| |
| 引用本文： | 尹笃林 银董红. 高区域选择合成对位柑菁酸甲酯中催化作用机理的研究[J]. 湖南师范大学自然科学学报, 1993, 16(2): 136-139 |
| |
| 作者姓名： | 尹笃林 银董红 |
| |
| 作者单位： | 精细催化合成研究所，湖南师大 92届有机催化硕士毕业生中南工业大学化学系 |
| |
| 摘 要： |
|
| 关 键 词： | 月桂烯 丙烯酸甲酯 柑菁酸甲酯 |
STUDIES ON THE CATALYTIC MECHANTSM IN HIGHLY REGIOSELECTIVE SYNTHESIS OF PARA-METHYL MYRACLATE |
| |
| Yin Dulin Ying Donghong. STUDIES ON THE CATALYTIC MECHANTSM IN HIGHLY REGIOSELECTIVE SYNTHESIS OF PARA-METHYL MYRACLATE[J]. Journal of Natural Science of Hunan Normal University, 1993, 16(2): 136-139 |
| |
| Authors: | Yin Dulin Ying Donghong |
| |
| Affiliation: | Institute of Fine Catalysis and Synthesis |
| |
| Abstract: | The mechanism of catalytic Diels-Alder reaction of myrcene and methyl acrylate with Lewis acid was investigated by UV,1R,~1HNMR and GC methods. It is found that myrcene difficutly interact with acid center,however,the coordination of methyl acrylate with acid center is strong and improved with increase of acid strength. Methyl myraclate was catalytically synthesised by AlCl_3 in mild condition,the yield is 64%mol and the content of para isomer is over 92%. |
| |
| Keywords: | myrcene methyl acrylate methyl myraclate Diels-Alder reaction catalysis reaction mechanism |
| 本文献已被 CNKI 维普 等数据库收录！ |
