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磷酸铝分子筛和硅磷酸铝分子筛作为羧酸酯化反应催化剂的研究
引用本文:赵瑞兰,何君. 磷酸铝分子筛和硅磷酸铝分子筛作为羧酸酯化反应催化剂的研究[J]. 湖南师范大学自然科学学报, 2000, 23(4): 40-45
作者姓名:赵瑞兰  何君
作者单位:湖南师范大学化学化工学院化学系,中国,长沙,410081
基金项目:湖南省教育厅科研项目,99C59,
摘    要:用新型磷酸铝分子筛和硅磷酸铝分子筛作催化剂合成了羧酸酯-丙酸丁酯和丙酸辛酯。考察了合成条件和催化剂制备方法对酯化反应的影响,并对酯产物做了红外光谱分析和物理性质测定,实测值接近文献值。

关 键 词:磷酸铝分子筛 硅磷酸铝分子筛 催化剂 酯化反应
修稿时间:2000-03-10

Studies on Esterification Reaction of Carboxylic Acid Using Aluminophosphate and Silicoaluminophosphate Molecular Sieves as Catalyste
ZHAO Rui-lan,HE Jun. Studies on Esterification Reaction of Carboxylic Acid Using Aluminophosphate and Silicoaluminophosphate Molecular Sieves as Catalyste[J]. Journal of Natural Science of Hunan Normal University, 2000, 23(4): 40-45
Authors:ZHAO Rui-lan  HE Jun
Abstract:Both butyl propionate and octyl propionate have been synthesized by the esterification reactions of carboxylic acid using novel aluminophosphate and silicoaluminophosphate molecular sieves as catalysts.The effects of reaction conditions and the methods of preparing the molecular sieve catalysts on the esterification reaction have also been investigated.The ester products were analysed by IR. And some other physical properties were also determined.The experimental values obtained were almost the same as the literature values.
Keywords:aluminophosphate molecular sieve  silicoaluminopho sphate molecular sieve  catalyst  carboxylic acid  esterfication  butyl propionate  octy1 propionate
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