| 3-芳基-3-（二烷氧基膦酰）丙酮酸酯的合成及表征 |
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| 引用本文： | 朱金龙,沈宗旋,张雅文.3-芳基-3-（二烷氧基膦酰）丙酮酸酯的合成及表征[J].苏州大学学报(医学版),2008,24(3):72-74. |
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| 作者姓名： | 朱金龙 沈宗旋 张雅文 |
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| 作者单位： | 苏州大学化学化工学院,江苏苏州215123 |
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| 摘 要： | 通过膦酸酯与草酸酯的缩合，合成了一系列新的3-芳基-3-（二烷氧基膦酰）丙酮酸酯，并对其结构进行了表征，该类化合物以酮式-烯醇式平衡混合物形式存在．
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| 关 键 词： | 3-(二烷氧基膦酰)丙酮酸酯 Arbuzov反应 缩合 |
3-Aryl substituted alkyl 3-dialkoxylphosphonopyruvates:synthesis,structural characterization |
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| Zhu Jinlong,Shen Zongxuan,Zhang Yawen.3-Aryl substituted alkyl 3-dialkoxylphosphonopyruvates:synthesis,structural characterization[J].Journal of Suzhou University(Natural Science),2008,24(3):72-74. |
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| Authors: | Zhu Jinlong Shen Zongxuan Zhang Yawen |
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| Institution: | ( School of Chemistry and Chemical Engineering, Suzhou Univ., Suzhou 215123, China) |
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| Abstract: | The synthesis and structural characterization of 3-aryl substituted alkyl 3-dialkoxylphosphonopyruvates through condensation of benzylphosphonates and oxalates were reported. This kind of compounds exist as a equilibrium mixture of keto-and enol-form. |
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| Keywords: | alkyl 3-dialkoxylphosphonopyruvates arbuzov reaction condensation |
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