| 1-乙炔基环辛醇合成及其在有机锡化合物合成中应用 |
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| 引用本文： | 任玉杰,陈惠麟. 1-乙炔基环辛醇合成及其在有机锡化合物合成中应用[J]. 大连理工大学学报, 2002, 42(3): 286-289 |
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| 作者姓名： | 任玉杰 陈惠麟 |
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| 作者单位： | 1. 大连理工大学,化工学院,辽宁,大连,116024
2. 中国科学院大连化学物理研究所,辽宁,大连,116023 |
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| 摘 要： | 在温和的反应条件下，使用叔丁醇钾做催化剂，使环辛酮在四氢呋喃中发生炔化反应（引入=健），获得了较好产率的1-乙炔基环辛醇，从1-乙炔基环辛醇出发，与ICl、Br2、I2反应合成了3种有机锡二卤化物，进而与含氯的双齿配体8-羟基喹啉（Oxin）配合，得到了互为同分异构体的3种配合物，并通过元素分析、锡含量测定，IR、^1HNMR测定对其结构进行了表征。
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| 关 键 词： | 1－乙炔基环辛醇 合成 有机锡化合物 炔化反应 表征 |
| 文章编号： | 1000-8608(2002)03-0286-04 |
Synthesis of 1-ethynyl-cyclooctanol and its application to preparation of organotin compounds |
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| REN Yu|Jie ,CHEN Hui|lin. Synthesis of 1-ethynyl-cyclooctanol and its application to preparation of organotin compounds[J]. Journal of Dalian University of Technology, 2002, 42(3): 286-289 |
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| Authors: | REN Yu|Jie CHEN Hui|lin |
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| Affiliation: | REN Yu|Jie 1,CHEN Hui|lin 2 |
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| Abstract: | At atmospheric pressure using uncomplexed potassium tert|butoxide as a catalyst, cyclooctanone is ethynylated in THF to give 1|ethynyl|cyclooctanol in good yield. Three compounds of organotin dichloride were prepared by the reactions of (Z)|1|[2|(triphenylstannyl)vinyl]cyclooctanol with ICl, Br 2,I 2. Three complexes were obtained by the reaction of the organotin dichlorides with 8|hydroxyquinoline. The compounds synthesized were characterized by means of elemental analysis, IR, 1HNMR. |
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| Keywords: | organotin compounds synthesis /1|ethynyl|cyclooctanol ethynylation characteristics |
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