| 固－液相转移催化合成环丙烷－1，1－二甲酸二乙酯 |
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| 引用本文： | 陈维誉,吴传炎.固－液相转移催化合成环丙烷－1，1－二甲酸二乙酯[J].河北大学学报(自然科学版),1996(1). |
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| 作者姓名： | 陈维誉 吴传炎 |
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| 作者单位： | 河北师范大学，河北轻化工学院 |
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| 摘 要： | 本文报道了在固液相转移催化条件下，将氟化钾浸渍的氧化铝作为强碱，季铵盐作为相转移催化剂（ＰＴＣ），合成环丙烷－１，１－二甲酸二乙酯，探讨了该反应的机理。
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| 关 键 词： | 相转移催化，氟阴离子，环丙烷－1．1－二甲酸二乙酯 |
Synthesis of Diethyl Cyclopropane-1,1-dicarboxylate by Solid-liquid Phase Transfer Catalysis |
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| Chen Weiyu, Wu Chuanyan.Synthesis of Diethyl Cyclopropane-1,1-dicarboxylate by Solid-liquid Phase Transfer Catalysis[J].Journal of Hebei University (Natural Science Edition),1996(1). |
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| Authors: | Chen Weiyu Wu Chuanyan |
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| Abstract: | Diethyl cyclopropane-1,1-dicarboxylate was synthesised using alumina coated with potassium fluoride as a strong base and quaternary ammonium salt as a phase transfer catalyst (PTC).Based on the experimental results a catalytic mechamism was proposed. |
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| Keywords: | Synthesis Phase transfer catalysis Fluoric anion Diethyl cyclopropane-1 1-dicarboxylate |
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