| 聚苯硫醚的合成、掺杂及其导电性 |
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| 引用本文： | 李晓常,焦扬声,李世瑨.聚苯硫醚的合成、掺杂及其导电性[J].华东理工大学学报(自然科学版),1987(5). |
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| 作者姓名： | 李晓常 焦扬声 李世瑨 |
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| 作者单位： | 华东化工学院高分子材料系
(李晓常，焦扬声)，华东化工学院高分子材料系(李世瑨) |
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| 摘 要： | 以对二氯苯和硫化钠为原料、苯甲酸钠为催化剂,加压缩聚合成了分子量较高的线型聚苯硫醚(PPS)。加入1,2,4-三氯化苯可获得支化PPS。用SbCl_5(溶于CH_3NO_2)掺杂PPS,可使其导电率从10~(-16) S/cm增加到10~(-2) S/cm。溶剂CH_3 NO_2能显著加快掺杂速率并改善最终掺杂材料的导电性。探讨了掺杂过程溶剂的作用机理。考察了掺杂时间、温度、聚苯硫醚结晶性对掺杂后材料导电性的影响。
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| 关 键 词： | 聚硫醚 缩聚 导电材料 锑化合物 五氯化锑 掺杂 |
Synthesis, doping and electrical conductivity of poly(p-phenylene sulfide) |
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| Li Xiaochang,Jiao Yangsheng,Li Shijin.Synthesis, doping and electrical conductivity of poly(p-phenylene sulfide)[J].Journal of East China University of Science and Technology,1987(5). |
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| Authors: | Li Xiaochang Jiao Yangsheng Li Shijin |
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| Institution: | Li Xiaochang;Jiao Yangsheng;Li Shijin Department of Polymer Materials |
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| Abstract: | By the polycondensation of 1,4-dichlorobenzene with sodium sulfide, poly(p-pheny-lene sulfide (PPS) with high molecular weight was synthesized. Various dopants wereinvestigated, and among those that has proved to be effective one is antimony pentachlo-ride (dissolved in nitromethane). The conductivity of SbCl_5-doped PPS can be increasedfrom 10~(16) S/cm to 10~(-2) S/cm. It was found that solvent nitromethane did play an im-portant role in enhancing the rate of doping. The influence of doping time, temperatureand the crystallinity of original PPS on the conductivity of doped PPS was also inves-tigated. |
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| Keywords: | polyphenylene sulfide polycondensation conductor materials antimony compounds doping antimony pentachloride |
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