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Efficient polymer light-emitting diodes with violet blue emission based on blends of PSiF6-PPP and PSiFC6C6
引用本文:TIAN Renyu MO Yueqi PENG Junbiao. Efficient polymer light-emitting diodes with violet blue emission based on blends of PSiF6-PPP and PSiFC6C6[J]. 科学通报(英文版), 2006, 51(22): 2805-2808. DOI: 10.1007/s11434-006-2185-y
作者姓名:TIAN Renyu MO Yueqi PENG Junbiao
作者单位:[1]School of Physics, South China University of Technology, Guangzhou510640, China [2]Institute of Polymer Optoelectronic Materials and Devices, SouthChina University of Technology, and Key Laboratory of SpeciallyFunctional Materials and Advanced Manufacturing Technology, Ministry of Education, G uangzhou 510640, China
基金项目:This work was supported by the National Natural Science Foundation of China (Grant Nos. 90201031 & 50573024), Key Project of Science and Technology, Ministry of Education (Grant No. 104208), and the State 973 Project (Grant No. 2002CB613405).
摘    要:Efficient polymer light-emitting diodes (PLEDs) with violet blue emission were fabricated using blends of copolymers of paraphenylene-co-silafluorene (PSiF6-PPP) and polymer of poly (9,9'-alkyl-3,6-silafluorene) (PSiFC6C6). The performances of the devices are sensitive to the blend ratio. When the mass ratio of PSiF6-PPP to PSiFC6C6 is 1 : 3, the highest external quantum efficiency is 1.96% at luminance of 105 cd.m2, its electroluminescent (EL) spectrum peaks at 398 nm and full width at half maximum is 67 nm. The improvements of the device performances were due to the energy transfer from PSiFC6C6 to PSiF6-PPP and the balanced injection of electrons and holes.

关 键 词:聚合体发光二极管 紫光蓝发光 能量转移 共聚物
收稿时间:2006-02-07
修稿时间:2006-02-072006-02-20

Efficient polymer light-emitting diodes with violet blue emission based on blends of PSiF6-PPP and PSiFC6C6
Renyu Tian,Yueqi Mo,Junbiao Peng. Efficient polymer light-emitting diodes with violet blue emission based on blends of PSiF6-PPP and PSiFC6C6[J]. Chinese science bulletin, 2006, 51(22): 2805-2808. DOI: 10.1007/s11434-006-2185-y
Authors:Renyu Tian  Yueqi Mo  Junbiao Peng
Affiliation:(1) School of Physics, South China University of Technology, Guangzhou, 510640, China;(2) Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, and Key Laboratory of Specially Functional Materials and Advanced Manufacturing Technology, Ministry of Education, Guangzhou, 510640, China
Abstract:Efficient polymer light-emitting diodes (PLEDs) with violet blue emission were fabricated using blends of copolymers of paraphenylene-co-silafluorene (PSiF6-PPP) and polymer of poly (9,9'-alkyl-3,6-silafluorene) (PSiFC6C6). The performances of the devices are sensitive to the blend ratio. When the mass ratio of PSiF6-PPP to PSiFC6C6 is 1 : 3, the highest external quantum efficiency is 1.96% at luminance of 105 cd.m2, its electroluminescent (EL) spectrum peaks at 398 nm and full width at half maximum is 67 nm. The improvements of the device performances were due to the energy transfer from PSiFC6C6 to PSiF6-PPP and the balanced injection of electrons and holes.
Keywords:polymer light-emitting diodes   violet blue emission   blend   energy transfer.
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