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Thermal simulation experiment on the hydrocarbon regeneration of marine carbonate source rock
作者姓名:LI  HuiLi  JIN  ZhiJun  HE  ZhiLiang  QIN  JianZhong  SHAO  ZhiBing
作者单位:[1]West Department of Petroleum Exploration and Production Research Institute, China Petroleum & Chemical Corporation, Urumq 830011, China [2]Petroleum Exploration and Production Research Institute, China Petroleum & Chemical Corporation, Beijing 100083, China [3]School of Energy Resources, China University of Geosciences, Beijing 100083, China [4]Wuxi Research Institute of Petroleum Geology, China Petroleum & Chemical Corporation, Wuxi 214151, China
基金项目:Support by the research project of "Hydrocarbon Accumulation and the Petroleum Exploration Strategy Around the Manjiaer and Awat Depressions. Tarim Basin" (Grant No. XBKY0303).The authors would like to thank Senior Engineer Zheng Lunju and others for their assistance in the thermal simulation experiments. The helpful comments of the anonymous reviewers are greatly appreciated.
摘    要:Hydrocarbon regeneration of marine carbonate source rock was simulated with thermal experiments in a laboratory. The results reveal that hydrocarbon regeneration does not simply continue the primary hydrocarbon generation process, and that, for marine carbonate source rock, discontinuous hydrocarbon generation differs greatly from the continuous generation. Several different features of hydrocarbon regeneration were observed in the experiments. First, the liquid hydrocarbon generation peak was always observed no matter what the initial maturity of the sample was. Moreover, the maturity and the liquid hydrocarbon yield corresponding to the peak varied with the sample’s initial maturity. Second, the hydrocarbon regeneration started earlier than the continuous one. In the experiments, the hydrocarbon could be re-generated when the sample maturity did not rise to any great extent. Third, the accumulative hydrocarbon-generating quantity during discontinuous generation was always more than that during continuous generation. And the hydrocarbon-generating quantity varied with the discontinuous generation history. Chemical kinetic analysis suggests that discontinuous hydrocarbon generation should not only be explained by the parallel reaction mechanism but also by the consecutive reaction mechanism which has been ignored in the traditional chemical kinetic model for continuous hydrocarbon generation.

关 键 词:碳氢化合物  碳酸盐  海洋  热模拟实验
收稿时间:18 June 2006
修稿时间:2006-06-182007-04-18

Thermal simulation experiment on the hydrocarbon regeneration of marine carbonate source rock
LI HuiLi JIN ZhiJun HE ZhiLiang QIN JianZhong SHAO ZhiBing.Thermal simulation experiment on the hydrocarbon regeneration of marine carbonate source rock[J].Chinese Science Bulletin,2007,52(14):1992-1999.
Authors:Li HuiLi  Jin ZhiJun  He ZhiLiang  Qin JianZhong  Shao ZhiBing
Institution:(1) West Department of Petroleum Exploration and Production Research Institute, China Petroleum & Chemical Corporation, Urumqi, 830011, China;(2) Petroleum Exploration and Production Research Institute, China Petroleum & Chemical Corporation, Beijing, 100083, China;(3) School of Energy Resources, China University of Geosciences, Beijing, 100083, China;(4) Wuxi Research Institute of Petroleum Geology, China Petroleum & Chemical Corporation, Wuxi, 214151, China
Abstract:Hydrocarbon regeneration of marine carbonate source rock was simulated with thermal experiments in a laboratory. The results reveal that hydrocarbon regeneration does not simply continue the primary hydrocarbon generation process, and that, for marine carbonate source rock, discontinuous hydrocarbon generation differs greatly from the continuous generation. Several different features of hydrocarbon regeneration were observed in the experiments. First, the liquid hydrocarbon generation peak was always observed no matter what the initial maturity of the sample was. Moreover, the maturity and the liquid hydrocarbon yield corresponding to the peak varied with the sample’s initial maturity. Second, the hydrocarbon regeneration started earlier than the continuous one. In the experiments, the hydrocarbon could be re-generated when the sample maturity did not rise to any great extent. Third, the accumulative hydrocarbon-generating quantity during discontinuous generation was always more than that during continuous generation. And the hydrocarbon-generating quantity varied with the discontinuous generation history. Chemical kinetic analysis suggests that discontinuous hydrocarbon generation should not only be explained by the parallel reaction mechanism but also by the consecutive reaction mechanism which has been ignored in the traditional chemical kinetic model for continuous hydrocarbon generation. Support by the research project of “Hydrocarbon Accumulation and the Petroleum Exploration Strategy Around the Manjiaer and Awat Depressions, Tarim Basin” (Grant No. XBKY0303)
Keywords:hydrocarbon regeneration  marine carbonate source rock  thermal simulation experiment  maturity  hydrocarbon-generating quantity  chemical kinetics
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