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热力学第三定律与经典理想气体模型的适用条件
引用本文:常琳,孟泉水.热力学第三定律与经典理想气体模型的适用条件[J].西安科技大学学报,2011,31(2).
作者姓名:常琳  孟泉水
作者单位:西安科技大学,理学院,陕西,西安,710054
摘    要:指出了经典理想气体与热力学第三定律不相容,在低温情况下,应考虑到量子效应的简并性,经典理想气体概念已不再适用.虽然绝对零度不能达到,但可用物理方法无限趋近它,目前的量级已达pK.

关 键 词:热力学第三定律  理想气体  绝对零度  

Universal anaysis of the third law of thermodynamics
CHANG Lin,MENG Quan-shui.Universal anaysis of the third law of thermodynamics[J].JOurnal of XI’an University of Science and Technology,2011,31(2).
Authors:CHANG Lin  MENG Quan-shui
Institution:CHANG Lin,MENG Quan-shui(College of Sciences,Xi'an University of Science and Technology,Xi'an 710054,China)
Abstract:The paper points out that the classical ideal gas is of exclusion with the third law of thermodynamics.At low temperatures it should think of the degenerate state of quantum effect,however,classical concepts is found wanting.Absolute zero can not be reached,but can be very close to it by physical means.In recent years,the order near to it has attained pK.
Keywords:third law of thermodynamics  ideal gas  absolute zero  entropy  
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