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Dipiphosphinoazines-from Rich Coordination Variability to Catalysis
Abstract:1 Results Diphosphinoazines are very versatile,potentially up to tetradentate ligands,known to form complexes with many transition metals.Recently,we developed synthesis of diphosphinoazines with various substituents on phosphorus donor atoms.This fine tuning allowed to design novel catalytic systems for several organic reactions.Hydroamination of Michael-type substrates with selected primary and secondary amines revealed the reactivity of some amines in non-catalyzed reaction.Hydroamination of methyl m...
Keywords:diphosphinoazines   transition metal complexes   catalysis  
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