| 反相纸色谱法研究几种烷基-苯基硫醚在HCl介质中的萃取和分离性能 |
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| 引用本文： | 胡澄文,许晓文,安荣洁,吴凤弟,张彦莉. 反相纸色谱法研究几种烷基-苯基硫醚在HCl介质中的萃取和分离性能[J]. 天津师范大学学报(自然科学版), 1993, 0(1) |
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| 作者姓名： | 胡澄文 许晓文 安荣洁 吴凤弟 张彦莉 |
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| 作者单位： | 天津师范大学化学系，南开大学化学系，南开大学化学系，南开大学化学系，南开大学化学系 |
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| 摘 要： | 合成了甲基-苯基硫醚,正丙基-苯基硫醚,正丁基-苯基硫醚和正庚基-苯基硫醚。确定了合成产物的组成和结构。用反相纸色谱法考察了四种硫醚在HCl介质中对30余种金属离子的萃取能力。并分别以四种硫醚为固定相对Au~Ⅲ(pd~Ⅱ)-pt~Ⅳ;Au~Ⅲ(pd~Ⅱ)-Os~Ⅳ(Pt~Ⅳ)-Ru~Ⅲ(Rh~Ⅲ);Pd~Ⅱ-Au~Ⅲ-Os~Ⅳ(Pt~Ⅳ)-Ru~Ⅲ(Rh~Ⅲ)等人工混合试液进行了纸上分离。
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| 关 键 词： | 苯基硫醚 无机离子的分离 反相纸色谱 |
STUDY ON THE EXTRACTION AND SEPARATION BEHAVIOR IN HYDROCHLORIC ACID OF A FEW ARALKYL SULFIDES BY REVERSED-PHASE PAPER CHROMATOGRAPHY |
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| Hu Chengwen,Xu Xiaowen,An Rongjie,Wu Fengdi and Zhang Yanli. STUDY ON THE EXTRACTION AND SEPARATION BEHAVIOR IN HYDROCHLORIC ACID OF A FEW ARALKYL SULFIDES BY REVERSED-PHASE PAPER CHROMATOGRAPHY[J]. Journal of Tianjin Normal University(Natural Science Edition), 1993, 0(1) |
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| Authors: | Hu Chengwen Xu Xiaowen An Rongjie Wu Fengdi Zhang Yanli |
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| Affiliation: | Hu Chengwen,Xu Xiaowen,An Rongjie,Wu Fengdi and Zhang Yanli Department of Chemistry,Tianjin Normal Umversity Department of Chemistry,Nankai University,Tianjin |
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| Abstract: | Four aralkyl sulfides, i.e. methyl phenyl sulfide, n-propyl phenyl sulfide,n-butyl phenyl sulfide, n-heptyl phenyl sulfide, were synthesized. The structuralcharacteristcs of these sulfides were determined. Its extraction behavior to more than 30metal ions in HCl systems were observed by reversed-paper chromatography. The datashow that, these sulfides can be used as a stationary phase in reversed-phase paperchromatography to separate some metalion mixtures, such asPd-Au-Os (Pt)-Ru(Rh)and others. |
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| Keywords: | aralkyl sulfid separation of inorganic ions reversed-phase paper chromatography |
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