| 烯丙基季磷盐的合成与表征 |
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| 引用本文： | 刘少祯,李红梅,卢敏,姚大虎,张玉清.烯丙基季磷盐的合成与表征[J].河南科技大学学报(自然科学版),2011,32(3):89-91,113. |
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| 作者姓名： | 刘少祯 李红梅 卢敏 姚大虎 张玉清 |
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| 作者单位： | 1. 河南科技大学高分子科学与纳米技术重点实验室,河南洛阳,471003
2. 河南科技大学高分子科学与纳米技术重点实验室,河南洛阳471003;洛阳师范学院化学化工学院,河南洛阳471022 |
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| 基金项目： | 国家自然科学基金项目(20902043); 国家科技部科技人员服务企业行动项目(SQ2009GJD0004653) |
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| 摘 要： | 采用两步合成法,用烯丙基溴和三苯基磷为原料,以四氯化碳为溶剂合成中间体溴化烯丙基三苯基磷盐(ATPH]+Br-)。经阴离子交换合成新型的季磷盐ATPH]+PF6-和ATPH]+BF4-。对3种产物的溶解性进行了考察;用IR、1HNMR对目标产物进行了结构表征;用DSC对产物熔点进行了测定。
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| 关 键 词： | 季磷盐 三苯基磷 烯丙基溴 |
Synthesis and Characterization of Allyl Phosphonium Salt Electrolytes |
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| LIU Shao-Zhen,LI Hong-Mei,LU Min,YAO Da-Hu,ZHANG Yu-Qing.Synthesis and Characterization of Allyl Phosphonium Salt Electrolytes[J].Journal of Henan University of Science & Technology:Natural Science,2011,32(3):89-91,113. |
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| Authors: | LIU Shao-Zhen LI Hong-Mei LU Min YAO Da-Hu ZHANG Yu-Qing |
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| Institution: | LIU Shao-Zhen1,LI Hong-Mei1,2,LU Min1,YAO Da-Hu1,ZHANG Yu-Qing1 (1.The key Lab of Polymer Science & Nanotechnology,Henan University of Science & Technology,Luoyang 471003,China,2.College of Chemistry & Chemical Engineering,Luoyang Normal University,Luoyang 471022,China) |
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| Abstract: | Allyl phosphonium salt(+Br-) was synthesized by using allyl bromide and triphenylphosphine.Two new allyl phosphonium salts,+PF-6 and + BF-4,were obtained by ionic exchanging +Br-with Potassium hexafluorophosphate and Sodium fluoroborate.The solubility of the products were investigated.The characterization of the target products were analyzed by IR and 1H NMR,and the melting points of the products were determined by DSC. |
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| Keywords: | Allyl phosphonium salt Triphenylphosphine Allyl bromide |
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