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铁和铈对铝在3.5%NaCl溶液中腐蚀行为的影响
引用本文:陈红梅,范常有,赵茂密,钟夏平.铁和铈对铝在3.5%NaCl溶液中腐蚀行为的影响[J].广西科学,2011,18(2):153-157.
作者姓名:陈红梅  范常有  赵茂密  钟夏平
作者单位:1. 广西大学物理科学与工程技术学院,广西南宁,530004
2. 广西科学院,广西南宁,530007
基金项目:国家自然科学基金项月,广西青年基金,广西研究生教育创新计划项目
摘    要:采用高频熔炼方法制备Al-Fe-Ce合金,通过X射线衍射仪、金相显微镜、电化学工作站等对制备的合金结构、动电位线性扫描极化曲线、浸泡与电化学腐蚀前后表面形貌的变化进行研究,并分析Al-Fe-Ce合金在浓度为3.5%NaCl溶液中耐腐蚀性能。结果表明:在3.5%NaCl溶液中腐蚀,Cl-致使铝合金容易发生点蚀;稀土Ce的加入能够改善合金微观结构,细化晶粒,减弱Cl-离子对点蚀的影响;合金中Ce的存在能够降低Fe对合金腐蚀性能的损害作用。

关 键 词:合金  铝-铁-铈  电化学  腐蚀行为
收稿时间:2010/10/8 0:00:00
修稿时间:2011/3/25 0:00:00

Effects of Fe and Ce on Corrosion Behaviors of Aluminum in 3.5% NaCl Solution
CHEN Hong-mei,FAN Chang-you,ZHAO Mao-mi and ZHONG Xia-ping.Effects of Fe and Ce on Corrosion Behaviors of Aluminum in 3.5% NaCl Solution[J].Guangxi Sciences,2011,18(2):153-157.
Authors:CHEN Hong-mei  FAN Chang-you  ZHAO Mao-mi and ZHONG Xia-ping
Institution:1.College of Physics Science and Technology,Guangxi University,Nanning,Guangxi,530004,China;2.Guangxi Academy of Sciences,Nanning,Guangxi,530007,China)
Abstract:Al-Fe-Ce alloys were prepared by high-frequency melting.The structure of alloys,potentiodynamic linear polarization cure,and the changes of the surface morphology after immersion and electrochemical corrosion were investigated by X-ray diffraction,metallurgical microscope,and electrochemical analysis.The corrosion characteristic of Al-Fe-Ce alloys in 3.5% NaCl solution was systematically analyzed.The results indicate that the addition of rare earth Ce in aluminum can refine the microstructure of alloy,and reduce the harmful effects of Cl-ions on pitting corrosion resistance.Furthermore,the addition of Ce in aluminum alloys can eliminate the damage of Fe to the corrosion resistance of alloys.
Keywords:alloys  Al-Fe-Ce  electrochemistry  corrosion behavior
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