| 肉桂酸酯化酚醛树脂季铵盐制备及光交联研究 |
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| 引用本文： | 甘志伟,黄树槐,谢洪泉.肉桂酸酯化酚醛树脂季铵盐制备及光交联研究[J].华中科技大学学报(自然科学版),2001,29(9):106-108. |
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| 作者姓名： | 甘志伟 黄树槐 谢洪泉 |
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| 作者单位： | 1. 华中科技大学材料科学与工程学院
2. 华中科技大学化学系 |
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| 摘 要： | 通过对酚醛环氧树脂的肉桂酸酯化及离子化改性，合成了肉桂酸酯化粉醛树脂季铵盐，并以它的溶解性和光固化性能进行了研究，结果表明：该产物可较好地溶于一些有机溶剂中，同时又是一种具有良好水溶性的感光高分子物质，覆盖防氧膜、添加活性稀释性单体及延长曝光时间有利于其光交联反应的进行。
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| 关 键 词： | 肉桂酸酯 水溶性高分子 酚醛环氧树脂 光交联 季铵盐 溶解性 光固化性 |
| 文章编号： | 1000-8616(2001)09-0106-03 |
| 修稿时间： | 2001年5月9日 |
Synthesis of Cinnamate and Quaternary Ammonium Salt-contained Phenolic Resin and Its Potocrosslinking |
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| Gan Zhiwei Huang Shuhuai Xie Hongquan Docotoral Candidate, College of Material Sci. & Eng.,HUST,Wuhan ,China..Synthesis of Cinnamate and Quaternary Ammonium Salt-contained Phenolic Resin and Its Potocrosslinking[J].JOURNAL OF HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY.NATURE SCIENCE,2001,29(9):106-108. |
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| Authors: | Gan Zhiwei Huang Shuhuai Xie Hongquan Docotoral Candidate College of Material Sci & Eng HUST Wuhan China |
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| Institution: | Gan Zhiwei Huang Shuhuai Xie Hongquan Docotoral Candidate, College of Material Sci. & Eng.,HUST,Wuhan 430074,China. |
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| Abstract: | Phenolic resin contained cinnamate and ion salt groups is synthesized by ring opening reaction of epoxy groups of epoxy phenolic resin with cinnamic acid and an ionization reagent. Solubility and UV photocuring properties are also investigated in this paper. Chinnamate and ion salt contained phenolic resin show very good solubility in water and some organic solvents, such as ethanol, chloroform, and DMF. It is shown that overlaying oxygen barrier layer, appending active diluent monomer and prolonging exposure time are in favor of the photopolymerization of the product. |
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| Keywords: | cinnamate water soluble polymer epoxy phenolic resin photocrosslinking quaternary ammonium salt |
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