| 嵌接式酞菁材料合成及其双氧水体系催化性能 |
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| 引用本文： | 胡希明,古国榜,何志梅,黄仲涛. 嵌接式酞菁材料合成及其双氧水体系催化性能[J]. 华南理工大学学报(自然科学版), 1996, 0(8) |
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| 作者姓名： | 胡希明 古国榜 何志梅 黄仲涛 |
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| 作者单位： | 华南理工大学应用化学系 华南理工大学化学工程系 |
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| 基金项目： | 国家教委留学回国人员基金，中国石油化工总公司发展基金，广东省科学基金 |
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| 摘 要： | 采用苯酐尿素在位合成新途径进行金属酞菁配合物嵌接式层状锑磷酸材料的合成制备工作。通过X射线衍射和红外光谱对在位反应过程及纯化材料进行了考察研究。用双氧水体系考评铁酞菁配合物嵌接式层状锑磷酸和钴酞菁配合物嵌接式层状锑磷酸材料的催化性能。
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| 关 键 词： | 酞菁 层状锑磷酸 嵌接式层状材料 合成 表征 双氧水 氧化催化 |
SYNTHESIS OF INTERCALATED PHTHALOCYANINES AND THEIR CATALYTIC BEHAVIOUR IN HYDROPEROXIDE SOLUTION |
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| Hu Ximing,Gu Guobang,He Zhimei,Huang Zhongtao. SYNTHESIS OF INTERCALATED PHTHALOCYANINES AND THEIR CATALYTIC BEHAVIOUR IN HYDROPEROXIDE SOLUTION[J]. Journal of South China University of Technology(Natural Science Edition), 1996, 0(8) |
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| Authors: | Hu Ximing Gu Guobang He Zhimei Huang Zhongtao |
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| Abstract: | Cobalt phthalocyanine and iron phthalocyanine as guest molecules have been prepared in situ in the layered phosphotoantimonic acid with an excess of phthalic anhydride, carbamide and some additives. The powder X ray diffraction data and infrared spectra revealed the expanded interlayer spacing and the formation of metal phthalocyanine, which provides the evidence that the intercalation of metal phthalocyanine in the layered phosphotoantimonic acid took place. In hydroperoxide solution, both the synthesized biomimetic materials CoPcSbP and FePcSbP showed much better behaviour than the not intercalated cobalt phthalocyanine and iron phthalocyanine,especially much improved catalytic stability in oxidation condition. |
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| Keywords: | phthalocyanine layered phosphotoantimonic acid intercalated layered material synthesis characterization hydroperoxide oxidation catalysis |
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