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Influence of interactions between chromium and cerium on catalytic performances of CrO_x–CeO_2/Ti-PILC catalysts for deep oxidation of n-butylamine
基金项目:supported by the National Natural Science Foundation of China (21177110)
摘    要:A series of CrOx-CeO2/Ti-PILC (PILC is pillared interlayered clay) catalysts for n-butylamine oxidation were prepared using an impregnation method, and the structures, surface acidity distributions, and redox properties of the catalysts were characterized using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, H2 temperature-programmed reduction, and NH3 temperature-programmed desorption. The results show that addition of an appropriate amount of CeO2 enhances the interactions between Cr and Ce, and this increases the acid strength and mobility of active oxygen species on the cata- lyst. 8CrCe(6:1)/Ti-PILC(12,20) exhibits the best catalytic performance and control of NOx in n-butylamine oxidation.

关 键 词:失活催化剂  相互作用  氧化铈  催化性能  深度氧化  X射线光电子能谱法  正丁胺  透射电子显微镜
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