| 用轨道相互作用观点讨论反应分子在金属催化剂上的催化活化机理 |
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| 引用本文： | 卢祥生,沐来龙. 用轨道相互作用观点讨论反应分子在金属催化剂上的催化活化机理[J]. 徐州师范大学学报(自然科学版), 1996, 0(4) |
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| 作者姓名： | 卢祥生 沐来龙 |
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| 作者单位： | 徐州师范大学化学系 |
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| 摘 要： | 本文从分子轨道对称守恒原理出发，讨论了一些对称禁阻有机协同反应在金属催化剂的作用下，由于反应物的分子轨道与金属催化剂表面原子的轨道发生相互作用，由原来的对称禁阻变成了对称允许的催化活化机理．
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| 关 键 词： | 分子轨道，对称性，催化活性 |
Discussion on Catalysis activation Mechanism of Metal Catalyst with the point of view of Orbital interaction |
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| Lu Xiangsheng,Mu Lailong. Discussion on Catalysis activation Mechanism of Metal Catalyst with the point of view of Orbital interaction[J]. Journal of Xuzhou Normal University(Natural Science Edition), 1996, 0(4) |
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| Authors: | Lu Xiangsheng Mu Lailong |
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| Abstract: | in this paper, with the point of view of molecular symmetry conservationprinciple, it was discussed that some symmetry-forbidden reactions become symmetry-allowedones because of the interaction between molecular orbitals of reactants and atomic orbitals ofmetal catalyst surface. |
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| Keywords: | Molecular orbital symmetry catalysis activation |
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