| 含氮手性离子液体的合成及应用研究进展 |
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| 引用本文： | 尹建军,孙华雨,朱颖,高洋. 含氮手性离子液体的合成及应用研究进展[J]. 兰州理工大学学报, 2008, 34(6) |
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| 作者姓名： | 尹建军 孙华雨 朱颖 高洋 |
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| 作者单位： | 兰州理工大学,石油化工学院,甘肃,兰州,730050;兰州理工大学,石油化工学院,甘肃,兰州,730050;兰州理工大学,石油化工学院,甘肃,兰州,730050;兰州理工大学,石油化工学院,甘肃,兰州,730050 |
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| 基金项目： | 甘肃省自然科学基金 |
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| 摘 要： | 综述咪唑鎓盐、季铵盐和吡啶鎓盐等含氮手性离子液体的合成及其在不对称催化反应中的应用研究进展.研究成果表明,手性离子液体的制备既可以直接使用手性源(如氨基酸、氨基醇、或生物碱等),也可以利用不对称合成.含氮手性离子液体手性中心的构建、固载化方法以及构效关系将是今后研究工作的重点.
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| 关 键 词： | 手性离子液体 不对称催化 有机合成 应用 |
Research advance of synthesis of nitrogenous chiral ionic liquids and its application |
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| YIN Jian-jun,SUN Hua-yu,ZHU Ying,GAO Yang. Research advance of synthesis of nitrogenous chiral ionic liquids and its application[J]. Journal of Lanzhou University of Technology, 2008, 34(6) |
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| Authors: | YIN Jian-jun SUN Hua-yu ZHU Ying GAO Yang |
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| Affiliation: | YIN Jian-jun,SUN Hua-yu,ZHU Ying,GAO Yang(College of Petrochemical Technology,Lanzhou Univ.of Tech.,Lanzhou 730050,China) |
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| Abstract: | The research advance of synthesis of various nitrogenous chiral ionic liquids such as imidazolium,ammonium,pyridinium,etc.and its application in asymmetric catalytic reactions was summarized.The chiral ionic liquids were prepared either from the chiral pool such as aminoacids,aminoalcohols,or alkaloids,or by asymmetric synthesis.The future study focus will be put on the construction of chiral center,preparation methods of immobilised chiral ionic liquids,and research of relations between structure and chara... |
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| Keywords: | chiral ionic liquids asymmetric catalysis organic synthesis application |
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