| 取代萘磺化反应的分子力学研究 |
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| 引用本文： | 林静 陈明旦. 取代萘磺化反应的分子力学研究[J]. 厦门大学学报(自然科学版), 1994, 33(6): 819-822 |
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| 作者姓名： | 林静 陈明旦 |
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| 摘 要： | 研究一系列甲氧基取代萘磺化反应，考察立体效应对反应的影响，并通过了分子力学ＤＴＭＭ程序计算及相应核磁谱数据解释反应结果。
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| 关 键 词： | 甲氧基 萘 衍生物 磺化反应 分子力学 |
Application of Molecular Mechanics in study of the Sulfonation Reaction of Naphthalene Derivatives |
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| Lin Jing,Chen Mingdan,Chen Li,Lin min,Huang Haishui. Application of Molecular Mechanics in study of the Sulfonation Reaction of Naphthalene Derivatives[J]. Journal of Xiamen University(Natural Science), 1994, 33(6): 819-822 |
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| Authors: | Lin Jing Chen Mingdan Chen Li Lin min Huang Haishui |
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| Affiliation: | Dept.of Chem. |
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| Abstract: | The reactions of naphthalene derivatives with CLSO_3 SiMe_3 were stdied.1-Methoxynaphthalene and 1,7-dimethoxynaphthalene were only monosulfonatied usingboth 1.0and 4.0 mole of CLSO_3 SiMe_3.Sulfonation of 1,6-dimethoxynaphthalene with 4.0mole of CLSO_3 SiMe_3,initially gave the 4-sulfonic acid.The reaction of 2,3-dimethoxy -naph-thalene with 1.0mole of CLSO_3 SiMe_3,yield the 5-and 6-monosulfonic acid products and the5,7-disulfonic acid product.The effect of steric hindrance on substitution positions were alsoexamined.The results were explained by molecular mechanics and 'HNMR data. |
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| Keywords: | Methoxynaphthalenes Sulfonation Molecular mechanics |
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