| 用Raman光谱研究P_2O_5和M_0O_3对钠硼硅玻璃结构的影响 |
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| 引用本文： | 张超武,叶瑞伦. 用Raman光谱研究P_2O_5和M_0O_3对钠硼硅玻璃结构的影响[J]. 齐齐哈尔大学学报(自然科学版), 1989, 0(2) |
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| 作者姓名： | 张超武 叶瑞伦 |
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| 作者单位： | 齐齐哈尔轻工学院(张超武)，武汉工业大学(叶瑞伦) |
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| 摘 要： | 本文用Raman光谱研究了钠硼硅基础玻璃的结构及高价氧化物P_2O_5和M_0O_3对其结构的影响。结果表明,钠硼硅玻璃结构符合“基因模型”理论,M_0O_3以其阳离子的高场强作用使结构中三配位硼增加,而P_2O_5受配位关系制约使结构中四配位硼增加。
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| 关 键 词： | 钠硼硅玻璃 Raman光谱 高价氧化物 三配位 四配位 玻璃 |
By Means of Raman spectrum investigating Sodium Borosilicate glass Structure Influenced by P_2O_5 anb M_0O_3 |
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| Zhang Chaowu Ye Ruilun. By Means of Raman spectrum investigating Sodium Borosilicate glass Structure Influenced by P_2O_5 anb M_0O_3[J]. Journal of Qiqihar University(Natural Science Edition), 1989, 0(2) |
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| Authors: | Zhang Chaowu Ye Ruilun |
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| Affiliation: | Zhang Chaowu Ye Ruilun(Qigihar Light Industrial Institute) (Wuhan University of Technology) |
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| Abstract: | The structure of sodium borosilicate base glass and the effects of P2O5 and M0O3 were studied in this paper by means of Raman spectrum. The results showed that the structure of base glass is in accord with the theory of the Group Models. M0O3 induces the number of BO3 triangles to increase for its high cationic field strenghth, otherwise P2O5 increases that of BO4 tetraheara because of the limit of its coordination. |
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| Keywords: | Sodium borosilicate glass Raman spectrum High-valence oxide Triangles Tetrahedra Glass |
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