| 4-(2,6-二氧杂-4,4-二溴甲基环己基)-N,N-二甲基苯胺的合成及结构表征 |
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| 引用本文： | 樊帆,肖昕,薛赛凤,祝黔江,陶朱.4-(2,6-二氧杂-4,4-二溴甲基环己基)-N,N-二甲基苯胺的合成及结构表征[J].贵州大学学报(自然科学版),2010,27(1):32-35. |
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| 作者姓名： | 樊帆 肖昕 薛赛凤 祝黔江 陶朱 |
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| 作者单位： | 贵州大学化学与化工学院,贵州省大环化学及超分子化学重点实验室,贵阳,550025 |
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| 基金项目： | 国家自然科学基金项目(20961002) |
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| 摘 要： | 从季戊四醇出发,合成了二溴新戊二醇。并利用二溴新戊二醇与对二甲胺基苯甲醛进行羟醛缩合反应,合成得到4-(2,6-二氧杂-4,4-二溴甲基环己基)-N,N-二甲基苯胺,并对其合成条件进行了优化。利用核磁共振技术、单晶X-射线衍射法、质谱、红外吸收光谱技术对目标产物的结构进行了表征。
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| 关 键 词： | 二溴新戊二醇 4-（2 6-二氧杂-4 4-2-溴甲基环己基）-N N-二甲基苯胺 核磁共振技术 单晶x-射线衍射法 质谱 |
The Synthesis and Characterization of 4-(2, 6-dioxaspiro-4, 4-dibromomethylcyclohexyl)-N,N-dimethylaniline |
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| FAN Fan,XIAO Xin,XUE Sai-feng,ZHU Qian-jiang,TAO Zhu.The Synthesis and Characterization of 4-(2, 6-dioxaspiro-4, 4-dibromomethylcyclohexyl)-N,N-dimethylaniline[J].Journal of Guizhou University(Natural Science),2010,27(1):32-35. |
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| Authors: | FAN Fan XIAO Xin XUE Sai-feng ZHU Qian-jiang TAO Zhu |
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| Institution: | 1.College of Chemistry and Chemical Engineering;Guizhou University;Guiyang 550003;China;2.Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province;Guiyang 550025;China |
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| Abstract: | Starting with pentaerythritol,2,2-Bis(bromomethyl)-1,3-propanediol was synthesized with the improved method.An aldol condensation between 2,2-Bis(bromomethyl)-1,3-propanediol and PQAB was carried out.The target product 4-(2,6-dioxaspiro-4,4-dibromomethylcyclohexyl)-N,N-dimethylaniline was obtained.The new compound was well-characterized including MS,IR,1H NMR spectroscopy,and X-ray single crystal diffraction. |
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| Keywords: | 4-(2 |
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