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Direct observation of monomer film structure of bacteriochlorophyll <Emphasis Type="Italic">c</Emphasis>
Authors:Yaxin?Jiang  Qingmin?Xu  Email author" target="_blank">Lijun?WanEmail author  Chen?Wang  Xiaohong?Fang  Chunli?Bai  Zhengyu?Wang  Tsunenori?Nozawa
Institution:(1) Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing, China;(2) Graduate School of Chinese Academy of Sciences, 100039 Beijing, China;(3) Department of Biochemistry, Graduate School of Engineering, Tohoku University, Aoba-04, 980-8579 Sendai, Japan
Abstract:The adsorption and assembling of bacteriochlorophyll c (BChl c) on a highly oriented pyrolytic graphite (HOPG) surface have been investigated by the scanning tunneling microscopy (STM). BChl c molecules are found to self-organize a well-defined adlayer on HOPG surface with a monomeric structure different from the dimer association seen on adlayers of Chls a, c and BChlide c, d. A structural model is proposed for the adlayer.
Keywords:bacteriochlorophyll c            HOPG  scanning tunneling microscopy  monomer film structure
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