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黄原酸钾的电位滴定法测定
引用本文:王玉琴,曹淑红,陈景文.黄原酸钾的电位滴定法测定[J].盐城工学院学报(自然科学版),2003,16(1):26-27,31.
作者姓名:王玉琴  曹淑红  陈景文
作者单位:1. 盐城工学院,化学工程系,江苏,盐城,224003
2. 盐城工学院,理化测试中心,江苏,盐城,224003
摘    要:报道了以银电极为指示电极,饱和甘汞电极为参比电极,在丙酮一氨水介质中,用硝酸银电位滴定法测定黄原酸钾的含量,滴定终点敏锐,方法简便、准确,相对标准偏差低于0.50%(n=5)。

关 键 词:黄原酸钾  电位滴定法  含量测定  分析化学  硝酸银  滴定终点  银电极
文章编号:1671-5322(2003)01-0026-02

Determination of Potassium Ethyl Xanthogenate by Potentiometric Titration
WANG Yu qin,CAO Shu hong,CHEN Jing wen.Determination of Potassium Ethyl Xanthogenate by Potentiometric Titration[J].Journal of Yancheng Institute of Technology(Natural Science Edition),2003,16(1):26-27,31.
Authors:WANG Yu qin  CAO Shu hong  CHEN Jing wen
Institution:WANG Yu qin 1,CAO Shu hong 1,CHEN Jing wen 2
Abstract:A novel method for determination of potassium ethyl xanthogenate in acetone-ammonia media by potentiometric titration, which employs the silver ion selective electrode as indicative electrode and the saturated calomel electrode as referred electrode, was developed. The test conditions were investigated. The experimental results under optimal conditions showed that the method was simple?fast with keen titration end point. It has been applied to determine potassium ethyl xanthogenate with satisfactory results, the relative standard deviations didn't exceed 0.50%.
Keywords:Potassium ethyl xanthogenate  ?ilver nitrate  ?Potentometric titration
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