| 新型2-取代8-羟基喹啉衍生物金属铝配合物的合成、表征及光物理研究 |
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| 引用本文： | 张成路,曲瑞峰,高丽娜,徐德青,赵宝成,朱长安,王雪.新型2-取代8-羟基喹啉衍生物金属铝配合物的合成、表征及光物理研究[J].辽宁师范大学学报(自然科学版),2013(1):71-75. |
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| 作者姓名： | 张成路 曲瑞峰 高丽娜 徐德青 赵宝成 朱长安 王雪 |
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| 作者单位： | 辽宁师范大学化学化工学院 |
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| 基金项目： | 辽宁省教育厅高校创新团队项目(2008T2017);辽宁省教育厅科学技术研究项目(2009A426) |
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| 摘 要： | 设计合成了2-（2′-二茂铁基）-乙烯基]-8-羟基喹啉（1）、2-（2′-BINOL基）-乙烯基]-8-羟基喹啉（2）及其金属铝配合物3和4.通过红外光谱（IR）和核磁共振谱（1 H NMR）等波谱测试技术对其结构进行了表征,结果表明成功实现了目标化合物的合成;通过电子吸收光谱（UV-Vis-NIR）及荧光光谱（EP）对配体1、2以及配合物3、4进行了光物理性质研究.结果显示配体2对Al 3＋离子具有强的选择识别功能,有望成为优良的离子识别添加剂;而配合物3在480nm处发出强蓝光,有望成为一种优良的蓝色电致发光材料.
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| 关 键 词： | 8-羟基喹啉 1 1′-联-2-萘酚 二茂铁 荧光光谱 |
The synthesis,characterization and photophysical properties of 2-substituted 8-hydroxyquinoline derivatives with Al complexes |
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| ZHANG Chenglu,QU Ruifeng,GAO Lina,XU Deqing, ZHAO Baocheng,ZHU Chang’an,WANG Xue.The synthesis,characterization and photophysical properties of 2-substituted 8-hydroxyquinoline derivatives with Al complexes[J].Journal of Liaoning Normal University(Natural Science Edition),2013(1):71-75. |
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| Authors: | ZHANG Chenglu QU Ruifeng GAO Lina XU Deqing ZHAO Baocheng ZHU Chang’an WANG Xue |
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| Institution: | (School of Chemistry and Chemical Engineering,Liaoning Normal University,Dalian 116029,China) |
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| Abstract: | The 2-2＇-（9H-ferrocen-2-yl] vinyl）-8-hydroxyquinoline（1） and 2-2＇-（BINOL-9-yl）vinyl]- 8-hydroxyquinoline（2） and their A1 complexes 3 and 4 have been synthesized,structure were success- fully confirmed by IR and I H NMR~the UV-Vis-NIR absorption spectra and fluorescence spectra of product 1,2 and complex 3,4 were determined in the room temperature,and analyzed in detail. The results show that product 2 has the strong selective identification function,is expected to become ex- cellent ion recognition additives~ complexe 3 emits strong blue light, is expected to become a good blue electroluminescent materials. |
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| Keywords: | 8-hydroxyquinoline BINOL ferrocene fluorescence spectrum |
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