Abstract: | Many trinary lanthanide complexes have been studied. However, few mixed anion complexes with bidentate heterocyclic amines were synthesized. We synthesized mixed anion complexes Ln ( CHi CICO0 )2 (NO3) (phen) which was determined by elemental analyses. The IR spectra analyses indicate that NO3 ,CH2 C1CO0- and phen are coordinated with Ln. The molar conductances of the complexes at 10-3 mol. L-1 were founded to be between 32.4 and 35.8 S. cma@mol- 1 , suggesting the nonelectrolytes in N Dimethylformamide. And we determined the fluorescent spectra Eu(CH2C1COO)2(NO3) ( phen ) and ESR spectra of Gd( CH2 ClC00 )2 ( NOs ) ( phen ) . |