| FeMo－co模拟物体系的性能表征 |
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| 引用本文： | 张凤章,黄静伟,杨如,许良树,张鸿图,万惠霖.FeMo－co模拟物体系的性能表征[J].厦门大学学报(自然科学版),1996(3). |
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| 作者姓名： | 张凤章 黄静伟 杨如 许良树 张鸿图 万惠霖 |
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| 作者单位： | 1Dept. of Biol.，2Dept. of Chem.，2 State Key Lab. for Phys. Chem. of the Solid Sur. |
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| 基金项目： | 国家基础性研究重大关键项目 |
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| 摘 要： | 根据蛋白键合ＦｅＭｏ－ｃｏ的Ｋ－Ｒ模型，合成了两个ＦｅＭｏ－ｃｏ模拟物的体系，这两个体系的可见光谱和Ｍｏ／Ｆｅ／Ｓ组成都接近于天然分离的ＦｅＭｏ－ｃｏ．模拟物体系经柠檬酸盐缓冲液稀释后，再与ＵＷ４５的组份１组合，都表现出高乙炔还原活性．
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| 关 键 词： | FeMo－co，模拟物，组合固氮酶，乙炔还原活性 |
The Characterization of the Systems of FeMo-co Modelling Compound |
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| Zhang Fengzhang,Huang Jingwei,Yang RuXu Liangshu, Zhang Hongtu,Wan Huilin.The Characterization of the Systems of FeMo-co Modelling Compound[J].Journal of Xiamen University(Natural Science),1996(3). |
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| Authors: | Zhang Fengzhang Huang Jingwei Yang RuXu Liangshu Zhang Hongtu Wan Huilin |
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| Institution: | Zhang Fengzhang1,Huang Jingwei2,Yang Ru2Xu Liangshu1, Zhang Hongtu2,Wan Huilin2 |
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| Abstract: | Two systems of FeMo-co modelling compound were synthesized according to the K-R model of protein-bonded FeMo-co. The visible spectrum and the composition of Mo/Fe/S for the two systems were similar to those of FeMo-co. Diluted with the citrate buffer and constituted with the component 1 of UW45, the two systems showed to have high C2H2 reductive activity. |
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| Keywords: | FeMo-co Modelling compound Constituted nitrogenase C_2H_2 reductive activity |
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