| 聚合物浓溶液中气液平衡估算 |
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| 引用本文： | 谢建军,潘勤敏,潘祖仁. 聚合物浓溶液中气液平衡估算[J]. 湘潭大学自然科学学报, 2000, 22(1): 30-36 |
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| 作者姓名： | 谢建军 潘勤敏 潘祖仁 |
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| 作者单位： | 1. 湘潭大学,高分子材料科学与工程研究所,湖南,湘潭,411105
2. 浙江大学高分子科学与工程研究所 |
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| 基金项目： | 国家自然科学基金，国家教委基金资助项目 |
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| 摘 要： | 采用UNIFAC、UNIFAC FV、GC FloryEOS模型 ,对PP、PIB、PBD、PMA、PnBMA、PVAC等几种聚合物和不同溶剂体系的气液平衡 (活度和无限稀重量分率活度系数 )进行了估算 .不同聚合物 /溶剂体系应选择不同的模型 ,这样才可使模型估算误差减小
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| 关 键 词： | 聚合物溶液 气液平衡 模型估算 UNIFAC |
Vapor-Liquid Equilibrium Calculations in Concentrated Polymer Solutions |
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| XIE Jian-jun,PAN Qin-min,PAN Zu-ren. Vapor-Liquid Equilibrium Calculations in Concentrated Polymer Solutions[J]. Natural Science Journal of Xiangtan University, 2000, 22(1): 30-36 |
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| Authors: | XIE Jian-jun PAN Qin-min PAN Zu-ren |
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| Abstract: | The models of UNIFAC, UNIFAC FV and group contribution equation of state(GC Flory EOS) have been used to calculate vapor liquid equibria (solvent activities and infinite dilute weight fraction activity coefficients) in a few concentrated polymer solutions such as PS, LDPE, PDMS, PP, PIB, PBD, PMA, PnBMA, PVAC, etc with various solvents. The results indicated that the different models should be used for the different polymer solutions in order to decrease the model estimation errors. |
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| Keywords: | polymer solutions vapor-liquid equilibrium model estimation UNIFAC UNIFAC-FV |
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