| 原子簇配位取代反应的红外光谱研究 |
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| 引用本文： | 杨秀利,曹艳萍,焦凤英,张聿照.原子簇配位取代反应的红外光谱研究[J].西安科技大学学报,2002,22(2):231-233. |
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| 作者姓名： | 杨秀利 曹艳萍 焦凤英 张聿照 |
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| 作者单位： | 1. 济南大学,化工学院,山东,济南,250022
2. 榆林高专,化学系,陕西,榆林,719000 |
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| 摘 要： | 利用红外光谱研究了十二羰基三钌和十二羰基三铁分别与二苯基硫脲的配位取代反应过程吸收光谱的变化情况。所得谱图数据揭示出原始物消失和新物质的形成过程。并对产物Ru3(CO) 9CSN2 HPh2 和Fe3(CO) 8S2 CNPh作了红外光谱测定
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| 关 键 词： | 三核钌簇 三核铁簇 配位取代反应 红外光谱 |
| 文章编号： | 1671-1912(2002)02-0231-03 |
| 修稿时间： | 2001年11月30 |
Study in coordination substitution of diphenyl sulfurine to trinuclear iron and ruthenium clusters by infrared spectrometry |
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| YANG Xiu li ,CAO Yan ping ,JIAO Feng ying ,ZHANG Yu zhao.Study in coordination substitution of diphenyl sulfurine to trinuclear iron and ruthenium clusters by infrared spectrometry[J].JOurnal of XI’an University of Science and Technology,2002,22(2):231-233. |
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| Authors: | YANG Xiu li CAO Yan ping JIAO Feng ying ZHANG Yu zhao |
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| Institution: | YANG Xiu li 1,CAO Yan ping 2,JIAO Feng ying 1,ZHANG Yu zhao 1 |
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| Abstract: | In this paper, infrared spectra were used in the characterization of the coordination substitution in which carbonyls in trinuclear ruthenium cluster and trinuclear iron cluster were substitued by diphenyl sulfurine respectively. Infrared spectra were used in characterization of the reactions and to follow the reaction processes from starting to finishing. Spectra data showed that the new compounds appear and starting materials disappear. The result products Ru 3(CO) 9CSN 2HPh 2 and Fe 3(CO) 8S 2CNPh were taken in KBr pellet infrared. |
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| Keywords: | trinuclear ruthenium cluster trinuclear iron cluster coordination substitution infrared spectra |
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