| 有机合成中杂多酸催化应用研究十九年 |
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| 引用本文： | 蔡天锡.有机合成中杂多酸催化应用研究十九年[J].大连理工大学学报,1999,39(2):208-213. |
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| 作者姓名： | 蔡天锡 |
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| 作者单位： | 大连理工大学碳资源综合利用开放研究实验室!辽宁大连，116012 |
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| 摘 要： | 简要概括了作民在课题组１９年间有机合成中以杂多酸为催化剂所开展的研究成果，其中包括从Ｃ４混合物中异丁烯选择低聚，低级烯烃与醋酸的直接酯化，由马豆醛制造喃、杂多酸为改性剂的骨架镍和骨架钴上不饱和醛选择加氢制不饱和醇等研究成果，拓宽了杂多酸的催化研究领域。
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| 关 键 词： | 杂多酸 催化作用 氧化 还原 有机合成 |
Research and applications of heteropolyacid catalyst in organic synthesis over past 19 years |
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| CAI Tian-xi.Research and applications of heteropolyacid catalyst in organic synthesis over past 19 years[J].Journal of Dalian University of Technology,1999,39(2):208-213. |
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| Authors: | CAI Tian-xi |
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| Abstract: | This paper summarizes the results of research and applications of heteropolyacidcatalyst in organic synthesis in our research group over past 19 years. It mainly contains theresults of selective oligomerization of isobutene in C4 mixture, direct esterification of lower alkenewith acetic acid, production of furan from crotonaldehyde by vapor phase oxldation, selectivehydrogenation of unsaturated aldehydes over Raney catalysts modified by salts ofheteropolyacids, and so on. These studies have enlarged the field of research and applications ofheteropolyacids. |
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| Keywords: | heteropolyacid/acid catalysis reduction-oxidation property modifier |
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