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Mechanism of lithium insertion in carbons pyrolyzed at low temperature
Authors:Hongqi Xiang  Shibi Fang  Yingyan Jiang
Institution:(1) Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing, China;(2) Department of Chemistry, Tsinghua University, 100084 Beijing, China
Abstract:Carbons pyrolyzed at temperature ranging from 500°C to 1 000°C are promising materials for high-energy density lithium batteries. These carbons not only possess a capacity higher than the theoretical value of graphite, but also display a different electrochemical behavior from that of graphite. Mechanisms now available for this phenomenon are reviewed after the presentation of mechanism of lithiun intercalation in graphite. Based on the recent research, a new model for lithium insertion in carbons pyrolyzed at low temperature and sane ideas for further study are proposed.
Keywords:lithium ion batteries  anode  carbonaceous materials  mechanism
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