Mechanism of lithium insertion in carbons pyrolyzed at low temperature |
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Authors: | Hongqi Xiang Shibi Fang Yingyan Jiang |
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Institution: | (1) Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing, China;(2) Department of Chemistry, Tsinghua University, 100084 Beijing, China |
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Abstract: | Carbons pyrolyzed at temperature ranging from 500°C to 1 000°C are promising materials for high-energy density lithium batteries.
These carbons not only possess a capacity higher than the theoretical value of graphite, but also display a different electrochemical
behavior from that of graphite. Mechanisms now available for this phenomenon are reviewed after the presentation of mechanism
of lithiun intercalation in graphite. Based on the recent research, a new model for lithium insertion in carbons pyrolyzed
at low temperature and sane ideas for further study are proposed. |
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Keywords: | lithium ion batteries anode carbonaceous materials mechanism |
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