| 环糊精醛接枝含氨基纤维的制备与包合研究 |
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| 引用本文： | 温会涛,胡智文,王秉,郑海玲.环糊精醛接枝含氨基纤维的制备与包合研究[J].北京联合大学学报(自然科学版),2008,22(4). |
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| 作者姓名： | 温会涛 胡智文 王秉 郑海玲 |
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| 作者单位： | 浙江理工大学,先进纺织材料与制备技术教育部重点实验室,杭州,310018;浙江省环境保护科学设计研究院,杭州,310007;浙江理工大学,先进纺织材料与制备技术教育部重点实验室,杭州,310018 |
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| 基金项目： | 浙江省自然科学基金
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| 摘 要： | 为制备新型环糊精改性纤维,首先合成了6位环糊精单醛,然后通过还原氨化反应将其分别接枝到壳聚糖纤维和蚕丝纤维上,并以桂皮酸、草莓醛和环丙沙星、左氟沙星为客体分子,合成了包合芳香物质或药物分子的功能纤维.利用1 H NMR、FT IR、UV-vis表征了其相应的结构,考察了其包合性能.结果表明,该类功能纤维保留有环糊精的空腔结构,具有包合性能;同时也说明,利用环糊精醛对含氨基类纤维的还原氨化反应是制备新型环糊精改性功能纤维的通用方法.
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| 关 键 词： | 环糊精 壳聚糖纤维 蚕丝纤维 包合反应 功能纤维 |
Synthesis and Inclusion of Containing Amino Fiber Grafted with Cyclodextrin Monoaldehyde |
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| WEN Hui-tao,HU Zhi-wen,WANG Bing,ZHENG Hai-ling.Synthesis and Inclusion of Containing Amino Fiber Grafted with Cyclodextrin Monoaldehyde[J].Journal of Beijing Union University,2008,22(4). |
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| Authors: | WEN Hui-tao HU Zhi-wen WANG Bing ZHENG Hai-ling |
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| Institution: | WEN Hui-tao~(1,2),HU Zhi-wen~1,WANG Bing~1,ZHENG Hai-ling~1(1.Key Laboratory of Advanced Textile Materials , Manufacturing Technology,Ministry of Education,Zhejiang Sci-Tech University,Hangzhou 310018,China2.Environmental Science Research , Design Institute of Zhejiang Province,Hangzhou 310007,China) |
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| Abstract: | A novel kind of functional fiber was prepared by coupling cyclodextrin monoaldehyde to containing amino fiber in the presence of sodium cyanoborohydride,which can form inclusion complex with various guest molecules.The structures were confirmed by FT-IR and()~1H NMR spectroscopy and the inclusion ability and cyclodextrin grafted yield were examined by the use of phenolphthalein.The results showed that it is a common method to synthesis cyclodextrin-grafted amino fiber through the reductive amination reactio... |
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| Keywords: | cyclodextrin chitosan fiber silk fiber inclusion reaction functional fiber |
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