Studies on a selena-aza-crown ether: Synthesis and catalytic behavior in hydrosilylation |
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| Authors: | Xu Wei Liu Xiufang Lu Xueran Xu Hansheng |
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| Affiliation: | (1) Department of Chemistry, Wuhan University, 430072 Wuhan, China |
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| Abstract: | The synthesis of a new type of selena-aza crown ether-6-(4-nitrobenzyl)-1,4,7,10-selenatriazacyclododecane (L) derivated from phenylalamine, and its platinum (II) complex was described. The catalytic activity of this complex for the hydrosilylation of olefins by triethoxysilane was investigated. Supported by the Chinese National Natural Science Foundation and the Doctoral Special Grant from the State Education Commission of China. Xu Wei: born in 1969, Ph.D. graduate student |
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| Keywords: | selena-aza crown ether platinum complex synthesis hydrosilylation catalyst |
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